Development of metal complexes having active oxygen species by controlling of reaction cavity
Development of metal complexes having active oxygen species by controlling of reaction cavity
批准号:
19350029
负责人:
SUZUKI Masatatsu
金额:
$10.48万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (B)
财政年份:
2007
资助国家:
日本
项目状态:
已结题
起止时间:
2007 至 2009
中文摘要
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英文摘要
(μ-η^2:η^2-Peroxo)dicopper(II), bis(μ-oxo)dinickel(III), and (μ-1,2-peroxo)Fe(III)_2 complexes having a variety of dinucleating ligands were prepared. The copper complexes are capable of initiating the oxidation of aliphatic C-H bonds having BDEs from ~74-~92 kcal mol^<-1>. The nickel complexes are also capable of hydroxylating the m-xylyl linker of the supporting ligands. Oxidation ability of the diiron complexes was also investigated.
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Oxidation Reactivity of a Bis(μ-oxo)-dinickel(III) Complex : Arene Hydroxylation of the Supporting Ligand
双(μ-氧代)-二镍(III)配合物的氧化反应性:支持配体的芳烃羟基化
DOI:
--
发表时间:
2009
期刊:
Angew.Chem.Int.Ed. 48
影响因子:
--
作者:
[K. Honda, J. Cho, T. Matsumoto, J. Roh, H. Furutachi, T. Tosha, M. Kubo, S. Fujinami, T. Ogura, T. Kitagawa, M. Suzuki]
通讯作者:
M. Suzuki
チオラト基を含む三脚型配位子を用いたニッケル(II)錯体の合成と性質
含硫醇基三脚型配体镍(II)配合物的合成及性能
DOI:
--
发表时间:
2008
期刊:
影响因子:
--
作者:
[黒木智也, 鈴木正樹]
通讯作者:
鈴木正樹
「二核鉄中心で酸素分子を活性化-ペルオキソ錯体のモデル研究」化学
“双核铁中心氧分子的活化 - 过氧配合物的模型研究”化学
DOI:
--
发表时间:
2009
期刊:
影响因子:
--
作者:
[三島愛, 藤原好恒, 安倍学, 古舘秀樹,鈴木正樹]
通讯作者:
古舘秀樹,鈴木正樹
ホームページ等。
主页等
DOI:
--
发表时间:
期刊:
影响因子:
--
作者:
[]
通讯作者:
過酢酸イオンを含む鉄(III)錯体の合成と反応性
含全乙酸根离子的铁(III)配合物的合成和反应活性
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[東條知則, 鈴木正樹, ら]
通讯作者:
ら
共 38 条
Syntheses of Dimetal Complexes Capable of Oxidizing Alkanes and Arenes
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批准号:22350027
-
项目类别:Grant-in-Aid for Scientific Research (B)
-
资助金额:$12.73万
-
财政年份:2010
-
负责人:SUZUKI Masatatsu
-
依托单位:
Development of Functional Metal Complexes Having Active Oxygen Species Controlled by Coordination Sphere
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批准号:16074206
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$7.36万
-
财政年份:2004
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负责人:SUZUKI Masatatsu
-
依托单位:
Development of Highly Functionalized Dimetal Complexes
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批准号:12640536
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.3万
-
财政年份:2000
-
负责人:SUZUKI Masatatsu
-
依托单位:
Investigations of dioxygen activation mechanisms by dimetal complexes
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批准号:11228202
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$38.14万
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财政年份:1999
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负责人:SUZUKI Masatatsu
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依托单位:
Functionalization of Dimetal Complexes by Ligand Design
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批准号:10640540
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.37万
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财政年份:1998
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负责人:SUZUKI Masatatsu
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依托单位:
Syntheses and Reactivity of Diiorn-, Dicobalt-, and Dicopper-Dioxygen Complexes
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批准号:07454175
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$4.86万
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财政年份:1995
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负责人:SUZUKI Masatatsu
-
依托单位:
海外基金