Development of Novel Molecular Transformation Reaction and Functionalization, Based on the Stabilization of Open-Shell Molecules

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Basic research study on reactive intermediates provides opportunities not only to create functional molecules, but also to develop methods and apparatus that analyze the character of molecules. In this study, we investigated the reactivity of largely elusive localized singlet biradicals, which had been known as putative intermediates in homolytic reactions, and succeeded to generate long-lived singlet 2,2-dialkoxy substituted 1,3-biradicals. The basic research allowed us to open the new field of chemistry.