Synthesis and Conformation Analysis of δ-Amino Acid Related Peptides

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From a new viewpoint recognizing peptide nucleic acid monomers are recognized as δ-amino acids, conformation study was carried out for the peptides ofδ -amino acids and of their related non-native amino-acids. It was shown that the most fundamental δ-amino acid residue have very interesting conformation properties caused by favorable intra-residue hydrogen bond, and also that theoretical results correspond to the experimental ones.