Electrochemical Formation of Nanomultilayer Structures of Manganese Oxides Intercalated with Photofunctional Molecules

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We successfully electrodeposited layered manganese oxides intercalated with photofunctional molecules (porphyrin, ruthenium bipyridine comlex), electron transfer mediator (methyl viologen), and cationic surfactants with large hydrophobic moiety. Photo irradiation to the layered manganese oxide films with photofunctional molecules did not cause a significant photocurrent. On the other hand, cationic surfactants form an organic phase which functioned as a reaction field toward catalytic oxidation of hydroquinone.