Development of solid-state calcium-43 NMR

为研究生物化合物中钙原子和钙离子的分子动力学，提出了一种固体钙-43核磁共振仪。虽然~1H、~(13)C和~(15)~N核磁共振波谱对生物科学的发展产生了巨大的影响，但对生物化合物的~(43)C核磁共振知之甚少。在这项工作中，我试图发展半整数四极核的光谱分析的基本原理，并可能发展应用于生物分子的固态~(43)&gt；钙核磁共振这一尚未探索的领域。

A solid-state calcium-43 Nuclear Magnetic Resonance (NMR) is proposed for investigation of the molecular dynamics of calcium atoms and ions in biological compounds. Although ^1H, ^<13>C, and ^<15>N NMR spectroscopy has made a tremendous impact on the development of biological sciences, much less is known about calcium-43 NMR of biological compounds. In this work, I try to develop the fundamental of spectral analysis for half-integer quadrupole nuclei and possibly the unexplored field of solid-state ^<43>Ca NMR for applications to biological molecules.