Physical properties of stereoregular polymers able to produce films having guest molecules distributed with highly regular orientation

点击翻译按钮获取中文摘要

First we have succeeded in showing what kind of molecule can be co-crystallized with syndiotactic polystyrene(SPS) by making most of gelation conditions of SPS with a solvent, i. e., its molecular size and/or solubility parameter. Our conclusion will be useful for developing SPS films co-crystals with functional guest molecules such as metal coordination complex. Second, we have established the method for determining three-dimensional arrangements of fluorescent guest molecules even if the fraction of the guest is low. This method will be a powerful tool for invention of functional SPS films.