Development of Novel Catalysts Based on Organo Rare Earth Metal Complexes
Development of Novel Catalysts Based on Organo Rare Earth Metal Complexes
批准号:
21225004
负责人:
HOU Zhaomin
金额:
$136.12万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (S)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009-05-11 至 2014-03-31
中文摘要
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英文摘要
By use of the cationic half-sandwich rare earth alkyl catalysts, we have achieved the regio- and stereoselective copolymerization of various olefins to give new polymer materials that cannot be prepared by previous means. The cationic half-sandwich rare-earth alkyl complexes can also serve as unique catalysts for the addition of ortho-C-H bonds of various pyridines and anisoles to a variety of olefins, to afford new alkylated pyridine and anisole derivatives, respectively.We have synthesized a new family of heteromultimetallic polyhydride complexes and group 4 metal polyhydride complexes, and found that rare-earth/d-transition metal heteromultimetallic polyhydride complexes and a trinuclear titanium hydride cluster show reversible hydrogen addition and release reaction, and unprecedented dinitrogen activation, respectively.
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DOI:
10.1002/anie.200903660
发表时间:
2009-10
期刊:
Angewandte Chemie
影响因子:
--
作者:
[Yasumasa Takenaka;T. Shima;J. Baldamus;Z. Hou]
通讯作者:
Yasumasa Takenaka;T. Shima;J. Baldamus;Z. Hou
DOI:
10.1246/bcsj.20100003
发表时间:
2010-05
期刊:
Bulletin of the Chemical Society of Japan
影响因子:
4
作者:
[M. Nishiura;Z. Hou]
通讯作者:
M. Nishiura;Z. Hou
希土類金属を含む分子性カルコゲニドクラスターの合成と構造
含稀土金属硫族化物分子团簇的合成与结构
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[Kakinuma, Y., Kidani, S., Aoyama, T., 縄田浩志, 島隆則]
通讯作者:
島隆則
ハーフサンドイッチ型スカンジウム触媒によるエチレンとブタジエンの共重合
半夹心型钪催化剂乙烯与丁二烯共聚
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[T.Kimoto, J.Suda, 山本敦]
通讯作者:
山本敦
アミジナート配位子を有する希土類ポリヒドリド錯体の単離と構造解析
脒配体稀土聚氢化物配合物的分离和结构分析
DOI:
--
发表时间:
2010
期刊:
影响因子:
--
作者:
[佐々木拓也, 上田啓貴, 三浦英生, 藤井覚, T.Ikeda, 王海玉]
通讯作者:
王海玉
共 155 条
Multimetallic Catalysts Based on Rare Earth Hydride Clusters
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批准号:18065020
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$20.48万
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财政年份:2006
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负责人:HOU Zhaomin
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依托单位:
Development of novel catalysts based on rare earth complexes
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批准号:18205010
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项目类别:Grant-in-Aid for Scientific Research (A)
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资助金额:$32.45万
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财政年份:2006
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负责人:HOU Zhaomin
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依托单位:
New Polymerization Reactions by Dynamic Rare Earth Complexes
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批准号:14078224
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$15.87万
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财政年份:2002
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负责人:HOU Zhaomin
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依托单位:
Development of new rare earth metal polymerization catalysts
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批准号:13440203
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$3.58万
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财政年份:2001
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负责人:HOU Zhaomin
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依托单位:
DEVELOPMENT OF MIXED-LIGAND-SUPPORTED LANTHANIDE POLYMERIZATION CATALYSTS
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批准号:11640573
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$2.18万
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财政年份:1999
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负责人:HOU Zhaomin
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依托单位:
海外基金