Construction of polunuclear complexes with multistabilities and molecular design of control of metal ion array

在这一工作中，我们将重点放在腺苷的氢结合的多个相互作用上，即分子安排的控制因素。Two One-dimensional Manganese Complex， [Mn_2]（naphtmen）_2（L）]（ClO_4）·2Et_2O·2MeOH·H_2O and [Mn_2]（naphtmen）_2（HL）]（ClO_4）_2·MeOH通过使用混合配体和包括核obase moiety、6-氨基-9-β-羧乙磺酸（HL）和甘蓝型锰二核复合体合成[Mn_2]（naphthmen）_2（H_2O）_2]（ClO_4）_2 （naphthmen ^2_=N，N'-（1，1，2，2-四甲基苯甲酸） bis（naphthylidene-iminato）dianion）。锰盐型单元，其中是由phenoxo组连接的外平面二聚体，由HL配体连接到合成反模式形成单尺寸链结构的多羧基桥，其中每条链都是由核糖基化单元的氢键磁性隔离的。Cryomagnetic Studies揭示了两个复杂性显示SCM属性。

In this work, we focus on multiple interactions of hydrogen bondings of adenines as control factors of molecular arrangements. Two one-dimensional manganese complexes, [Mn_2(naphtmen)_2(L)](ClO_4)・2Et_2O・2MeOH・H_2O and [Mn_2(naphtmen)_2(HL)](ClO_4)_2・MeOH were synthesized by using a bridging ligand including a nucleobase moiety, 6-amino-9-β-carboxyethpurine (HL), and salen-type manganese dinuclear complex, [Mn_2(naphtmen)_2(H_2O)_2](ClO_4)_2 (naphtmen^2_=N,N'-(1,1,2,2-tetramethylethylene) bis(naphthylidene-iminato)dianion). Manganese salen-type units, which are out-of-plane dimer bridged by phenoxo groups, are linked by HL ligands thorough carboxylate bridges in syn-anti mode to form one-dimensional chain structure, where each chain is magnetically isolated by hydrogen bondings of nucleobase units. Cryomagnetic studies reveal that both complexes show SCM properties.