Research on Photofunctional Uranium(III) Complexes

光功能铀(III)配合物的研究

• 批准号: 21750059
• 负责人: NAKAI Hidetaka
• 金额: $ 3万
• 依托单位: Kyushu University (2010)Kanazawa University (2009)
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21750059/
• 关键词: 有機金属化学; 金属錯体化学; 光物性

An aim of this project is creation of photofunctional uranium(III) complexes. In order to achieve the aim, the research was focused on "the evaluation and development of photofuncitonal ligands" and "the establishment of synthetic methods of uranium(III) complexes". The obtained results are as follows :(1) Novel photofunctionalized triazacyclononane (TACN) ligands were successfully synthesized.(2) The terbium(III) complexes, which are mock complexes of the aimed uranium(III), were photo-physically characterized and valuable guidelines on how to design the ligands were obtained.(3) A convenient synthetic route of uranium(III) complexes was developed.

该项目的目的是创造光功能铀（III）配合物。为了达到这一目的，研究重点是“光功能配体的评价与开发”和“铀（III）配合物的合成方法的建立”。结果表明：(1)成功合成了新型光功能化三氮杂环壬烷（TACN）配体。(2)铽（III）配合物是靶铀（III）的模拟配合物，对其进行了光物理表征，获得了设计配体的有价值的指导。(3)开发了一种简便的铀（III）配合物合成路线。

项目成果

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