Precision Polymerization of Designed Phenol Toward New Material Chemistry of Phenolic Resin

设计苯酚的精密聚合促进酚醛树脂新材料化学

• 批准号: 21750116
• 负责人: KONISHI Gen-Ichi
• 金额: $ 2.83万
• 依托单位: Tokyo Institute of Technology
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Young Scientists (B)
• 财政年份: 2009
• 资助国家: 日本
• 起止时间: 2009 至 2010
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-21750116/
• 关键词: フェノール樹脂; 精密重合; 材料化学; デザイン型フェノール; 付加縮合; 透明樹脂; ポリマーブレンド; 立体規則性高分子; フィラー; 構造解析; 反応性高分子

Functional poly(phenylenemethylene)s as a new class of phenolic resins prepared by the polycondensation of alkoxybenzene derivatives such as anisole and trimethoxybenzene with formaldehyde are described. The unique polymerization behaviors and properties of the obtained alkoxylated novolacs can be attributed to the protected phenolic hydroxyl group. In this study, we have conducted new material chemistry of phenolic resin.

介绍了由苯甲醚、三甲氧基苯等烷氧基苯衍生物与甲醛缩聚制备的新型酚醛树脂--功能化聚亚苯基亚甲基。所得烷氧基化酚醛清漆独特的聚合行为和性能可归因于受保护的酚羟基。在本研究中，我们进行了酚醛树脂的新材料化学。

项目成果

Synthesis of a High Molecular Weight Bisphenol A Novolac

高分子量双酚 A 酚醛清漆的合成

• 期刊: Polym. J (in press)
• 作者: T. Nemoto;I. Amir;G. Konishi
• 通讯作者: G. Konishi

Novel Reactive Novolac : Synthesis of Alkoxylated Phenolic Resins Containing an Acetyl Group and Their Functionalization by Grignard Reaction

新型反应性酚醛清漆：含乙酰基的烷氧基化酚醛树脂的合成及其通过格氏反应的官能化

• 期刊: Polym. J. (in press)
• 作者: T. Nemoto;I. Amir;G. Konishi
• 通讯作者: G. Konishi

Synthesis and Analysis of Resorcinol-Acetone Copolymer" 14, 364-377 (2009)

间苯二酚-丙酮共聚物的合成与分析》 14, 364-377 (2009)

• 发表时间: 2009
• 期刊: Molecules
• 影响因子: 4.6
• 作者: A.Kobayashi;G.Konishi
• 通讯作者: G.Konishi

Synthesis of a Branched Poly (phenylene ethylene) with Bromomethyl Groups as a Processable and Functional Parylene

具有溴甲基基团的支化聚亚苯基乙烯的合成作为可加工的功能性聚对二甲苯

• 期刊: J.Appl.Polym.Sci. in press
• 作者: A.Kobayashi;K.Sumi;G.Konishi
• 通讯作者: G.Konishi

Synthesis and Evalution of Well-Defined High Molecular Weight Diphenyl Oxide and Diphenyl Sulfide Novolacs

明确的高分子量二苯醚和二苯硫醚酚醛清漆的合成和评价

• 发表时间: 2010
• 期刊: J.Appl.Polym.Sci. 118
• 作者: G.Konishi;Y.Nojiri;T.Matsuo;T.Nemoto;K.Asai;K.Sumi;Y.Nakamoto
• 通讯作者: Y.Nakamoto