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Organic and catalysis chemistry based on low-valent boron compounds

Organic and catalysis chemistry based on low-valent boron compounds
基于低价硼化合物的有机和催化化学
批准号:
21685006
负责人:
YAMASHITA Makoto
金额:
$18.14万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Young Scientists (A)
财政年份:
2009
资助国家:
日本
项目状态:
已结题
起止时间:
2009 至 2010

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项目成果

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中文摘要
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英文摘要
This research project has achieved the followings. (1) Exploration of chemistry of boryl anion, especially for the formation of boron-containing chemical bond with second-row p-block elements, and application of the resulting products for organic syntheses. (2) Attempt to synthesize boron-centered radical and low-oxidation state boron compound, borylene, and confirmation of photo-activated boryl radical species. (3) Syntheses and properties of transition-metal complexes bearing a boron-containing multidentate ligand and their application to catalysis.
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会议论文
DOI: 10.1021/om2010172
发表时间: 2011-11
期刊: Organometallics
影响因子: 2.8
作者: [R. Tanaka;M. Yamashita;L. Chung;K. Morokuma;K. Nozaki]
通讯作者: R. Tanaka;M. Yamashita;L. Chung;K. Morokuma;K. Nozaki
DOI: --
发表时间: 2011
期刊:
影响因子: --
作者: [H. Fukazawa, T. Ishida, H. Shirota., 高橋 講平・山下 誠・田中 善幸・野崎 京子]
通讯作者: 高橋 講平・山下 誠・田中 善幸・野崎 京子
Reduction of Base-Stabilized Difluoroborane Compounds witb One-Electron Reducing Agent
用单电子还原剂还原碱稳定的二氟硼烷化合物
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [Yoshitaka Aramaki, Makoto Yamashita, Kyoko Nozaki]
通讯作者: Kyoko Nozaki
DOI: --
发表时间: 2010
期刊:
影响因子: --
作者: [Yamashita, M. ; Suzuki, Y. ; Segawa, Y. ; Nozaki, K., 長谷川万紀・瀬川泰知・山下誠・野崎京子]
通讯作者: 長谷川万紀・瀬川泰知・山下誠・野崎京子
54
    Creation of highly reactive boron compounds by thorough utilization of vacant orbital
    • 批准号:
      17H01191
    • 项目类别:
      Grant-in-Aid for Scientific Research (A)
    • 资助金额:
      $28.62万
    • 财政年份:
      2017
    • 负责人:
      YAMASHITA Makoto
    • 依托单位:
    Precise elucidation of effect of boryl substituents: novel reactivity caused by a vacant orbital
    Solubilization and controlling physical properties of coal-tar-pitch as a source for carbon fiber: toward establishment of "bottom-up bulk chemistry"
    • 批准号:
      26620185
    • 项目类别:
      Grant-in-Aid for Challenging Exploratory Research
    • 资助金额:
      $2.5万
    • 财政年份:
      2014
    • 负责人:
      YAMASHITA Makoto
    • 依托单位:
    An iterative method for nonlinear semidefinite programming with the distance information to a cone boundary
    • 批准号:
      24710161
    • 项目类别:
      Grant-in-Aid for Young Scientists (B)
    • 资助金额:
      $1.91万
    • 财政年份:
      2012
    • 负责人:
      YAMASHITA Makoto
    • 依托单位:
    海外基金