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Formation and characterization of organogels showing a red emission triggered by complexation.

Formation and characterization of organogels showing a red emission triggered by complexation.
显示由络合引发的红色发射的有机凝胶的形成和表征。
批准号:
23550157
负责人:
TSUGE Akihiko
金额:
$3.41万
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (C)
财政年份:
2011
资助国家:
日本
项目状态:
已结题
起止时间:
2011 至 2013

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中文摘要
翻译
在这项研究中,已经完成了由络合引起的具有强烈红色发射的有机凝胶的形成。我们已经制备了具有尿素单元的配体然后这些配体与铕金属络合。我们发现,根据溶剂的不同,配合物可以形成具有强红色发射的有机凝胶。具有两个长烷基链的配体表现出胶凝能力及其配合物。有趣的是,具有三个长烷基链的配体即使在配位后也表现出弱的胶凝能力。
英文摘要
In this research formation of organogels showing a strong red emission triggered by complexation has been done. We have prepared the ligands having the urea units and then complexed these ligands with a europium metal. We have found out that the complexes can form the organogels exhibiting a strong red emission depending solvents used. The ligands having two long alkyl chains show the gelation ability as well as their complexes. Interestingly the ligands having three long alkyl chains show weak gelation ability even after complexation.
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会议论文
Organogelators Derived from [3.3]Metacyclophane Skeleton with a Urea Unit
源自带有尿素单元的 [3.3]Metacyclophane 骨架的有机凝胶剂
DOI: --
发表时间: 2012
期刊: Chem.Lett
影响因子: --
作者: [Akihiko Tsuge, Ryuichiro Matsushita, Katsuhiko Sakura, Tetsuji Moriguchi, Koji Araki]
通讯作者: Koji Araki
赤色発光型ユーロピウム錯体を用いたゲル化剤の開発
使用发红光的铕络合物开发胶凝剂
DOI: --
发表时间: 2013
期刊:
影响因子: --
作者: [池田脩, 森口哲次, 荒木孝司, 柘植顕彦]
通讯作者: 柘植顕彦
DOI: --
发表时间:
期刊:
影响因子: --
作者: [焼谷大輔, 森口哲次, 荒木孝司, 柘植顕彦]
通讯作者: 柘植顕彦
DOI: --
发表时间: 2013
期刊:
影响因子: --
作者: [池田脩, 森口哲次, 荒木孝司, 柘植顕彦]
通讯作者: 柘植顕彦
Construction and Characterization of Nano-structure based on acethylene macrocycles consisting of the fluorene units.
  • 批准号:
    14550827
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $1.98万
  • 财政年份:
    2002
  • 负责人:
    TSUGE Akihiko
  • 依托单位:
Preparation of Box-shaped Cyclophane Compounds Recognizing Endocrine Disruptors and their Immobilization
  • 批准号:
    11650900
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.05万
  • 财政年份:
    1999
  • 负责人:
    TSUGE Akihiko
  • 依托单位:
Immobilization of a Water-Soluble Host Molecule by Polyion Complexation with a Polymer
  • 批准号:
    09650942
  • 项目类别:
    Grant-in-Aid for Scientific Research (C)
  • 资助金额:
    $2.18万
  • 财政年份:
    1997
  • 负责人:
    TSUGE Akihiko
  • 依托单位:
海外基金