Anomalous Aggregation of Inorganic Anions into Ionic Nanostructures

无机阴离子异常聚集成离子纳米结构

• 批准号: 23651091
• 负责人: TAKUMI KONNO
• 金额: $ 2.41万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Challenging Exploratory Research
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011 至 2012
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23651091/
• 关键词: イオン結晶; 自己組織化

In this study, the creation of ionic nanostructures, in which complex cations are self-assembled through various, multiple non-covalent interactions accompanied by the unusual aggregation of inorganic anions into the interstices surrounded by cationic molecular aggregates, was investigated. This study evidenced that the introduction of multiple non-covalent interactions can lead to the aggregation of complex cations and that the close-packed arrangement of the created cationic aggregates in crystal results in the aggregation of a number of inorganic anions in its interstices.

在这项研究中，离子纳米结构的创建，其中复杂的阳离子是自组装通过各种，多种非共价相互作用，伴随着不寻常的聚集的无机阴离子到由阳离子分子聚集体包围的间隙，进行了研究。该研究证明，多种非共价相互作用的引入可以导致复杂阳离子的聚集，并且所产生的阳离子聚集体在晶体中的紧密堆积排列导致许多无机阴离子在其间隙中聚集。

项目成果

Rational creation of chiral multinuclear and metallosupramolecular compounds from thiol-containing amino acids

• DOI: 10.1039/c0dt01660h
• 发表时间: 2011-07-28
• 期刊: DALTON TRANSACTIONS
• 影响因子: 4
• 作者: Igashira-Kamiyama, Asako;Konno, Takumi
• 通讯作者: Konno, Takumi

A 1:1 intercluster compound consisting of +6 and -6 charged RhIII4ZnII4 octanuclear cations and anions with aminothiolate ligands

由 6 个和 -6 个带电 RhIII4ZnII4 八核阳离子和阴离子以及氨基硫醇配体组成的 1:1 簇间化合物

• DOI: 10.1039/c3ce41800f
• 发表时间: 2013
• 期刊: CrystEngComm
• 影响因子: 3.1
• 作者: Nobuto Yoshinari;Ukyo Yamashita and Takumi Konno
• 通讯作者: Ukyo Yamashita and Takumi Konno

Metallosupramolecular Architectures Controlled by Metal-Center Chirality of L-Cysteinato Cobalt(III) Octahedrons

L-半胱氨酸钴(III)八面体金属中心手性控制的金属超分子结构

• 发表时间: 2013
• 作者: T. Konno;T;Aridomi;N. Yoshinari;and A. Igashira-Kamiyama
• 通讯作者: and A. Igashira-Kamiyama

A Remarkable Metal-Crossing between Thiolato-Bridged Tetragold(I) and Tetrasilver(I) Metallorings

硫奥拉托桥四金 (I) 和四银 (I) 金属之间的显着金属交叉

• DOI: 10.1002/asia.201100668
• 发表时间: 2011
• 期刊: Chemistry an Asian Journal
• 作者: 今野巧;瀧野祐輔
• 通讯作者: 瀧野祐輔

Can We Create a Variety of Chiral Hererometallic Compounds from a Single Kind of Amino Acid?

我们能否从单一氨基酸中制备出多种手性异质金属化合物？

• 发表时间: 2011
• 作者: T. Konno;and N. Yoshinari;T. Konno;Takumi konno;今野巧;今野巧
• 通讯作者: 今野巧