reation of Metallosupramolecular Structures That Show Separate Aggregation of Cations and Anions

显示阳离子和阴离子单独聚集的金属超分子结构的反应

• 批准号: 23350026
• 负责人: TAKUMI KONNO
• 金额: $ 13.23万
• 依托单位: Osaka University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B)
• 财政年份: 2011
• 资助国家: 日本
• 起止时间: 2011-04-01 至 2014-03-31
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-23350026/
• 关键词: イオン結晶; 結晶工学; 自己組織化; 超分子化学; 超分子科学

In this study, the construction of ionic metallosupramolecular species, in which several complex-ions are self-assembled though multiple supramolecular interactions, together with the creation of metallosupramolecular architectures that show separate aggregation of cations and anions by the high-order aggregation of this class of metallosupramolecules, was investigated. As a result, the metal complexes containing both hydrophilic sulfur-containing amino acids and phenylphosphines was found to function as a multidentate metalloligand available for the construction of desirable metallosupramolecular structures. In addition, a significant insight into multiple supramolecular interactions that lead to the separate aggregation of cations and anions was obtained in this study.

在这项研究中，离子型金属超分子物种的建设，其中几个复杂的离子是自组装通过多个超分子相互作用，连同创建的金属超分子结构，显示单独的聚集阳离子和阴离子的这类金属超分子的高阶聚集，进行了研究。结果发现，含亲水性含硫氨基酸和苯基膦的金属配合物可以作为多齿金属配体，用于构建理想的金属超分子结构.此外，在这项研究中获得了一个显着的洞察到多重超分子相互作用，导致阳离子和阴离子的单独聚集。

项目成果

Aggregation of chiral hexanuclear complex-cations into cationic metallosupramolecules with concomitant aggregation of inorganic counter-anions into anionic clusters

• DOI: 10.1039/c2ce06539h
• 发表时间: 2012-01-01
• 期刊: CRYSTENGCOMM
• 影响因子: 3.1
• 作者: Lee, Raeeun;Igashira-Kamiyama, Asako;Konno, Takumi
• 通讯作者: Konno, Takumi

A 1:1 intercluster compound consisting of +6 and -6 charged RhIII4ZnII4 octanuclear cations and anions with aminothiolate ligands

由 6 个和 -6 个带电 RhIII4ZnII4 八核阳离子和阴离子以及氨基硫醇配体组成的 1:1 簇间化合物

• DOI: 10.1039/c3ce41800f
• 发表时间: 2013
• 期刊: CrystEngComm
• 影响因子: 3.1
• 作者: Nobuto Yoshinari;Ukyo Yamashita and Takumi Konno
• 通讯作者: Ukyo Yamashita and Takumi Konno

Synthesis and Structure of a Neutral Au^I₄Ni^II₂ Hexanuclear Complex Containing <small>D</small>-Penicillaminate and 1,2-Bis(diphenylphosphino)ethane

含<small>D</small的中性Au^I₄Ni^II₂六核配合物的合成与结构

• DOI: 10.1246/bcsj.20120024
• 发表时间: 2012
• 期刊: Bulletin of the Chemical Society of Japan
• 影响因子: 4
• 作者: A. Igashira-Kamiyama;N. Matsushita;R. Lee;K. Tsuge;and T. Konno
• 通讯作者: and T. Konno

Rational creation of chiral multinuclear and metallosupramolecular compounds from thiol-containing amino acids

• DOI: 10.1039/c0dt01660h
• 发表时间: 2011-07-28
• 期刊: DALTON TRANSACTIONS
• 影响因子: 4
• 作者: Igashira-Kamiyama, Asako;Konno, Takumi
• 通讯作者: Konno, Takumi

The First Crystal Structure of an Alkaline Metal Salt of Thioglucose: Potassium 1-Thio-β-D-glucoside Monohydrate

硫代葡萄糖碱金属盐的第一个晶体结构：1-硫代-β-D-葡萄糖苷一水合物钾

• DOI: 10.1107/s0108270112047014
• 发表时间: 2012
• 期刊: Acta Crystallogra., Sect.C
• 作者: 山根健史;佐藤和信;杉崎研司;豊田和男;塩見大輔;吉澤真;田所誠;工位武治;Nobuto Yoshinari
• 通讯作者: Nobuto Yoshinari