Development of Novel Synthetic Methods of Soluble Graphene Derivatives Having Transistor Performance
Development of Novel Synthetic Methods of Soluble Graphene Derivatives Having Transistor Performance
批准号:
23655090
负责人:
KAKIUCHI Fumitoshi
金额:
$2.5万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Challenging Exploratory Research
财政年份:
2011
资助国家:
日本
项目状态:
已结题
起止时间:
2011 至 2012
中文摘要
我们研究了芳香酮和芳基硼酸酯通过碳-氢、碳-氧和碳-氮键断裂偶联合成多环芳烃的进展,并考察了这些多环芳烃的应用:1)通过非活性碳键断裂的苯乙酮多芳基化和通过乙酰基转化的苯环结构的发展; 2)通过我们的多芳基化方案开发了具有石墨烯框架的多环芳烃的短合成的新方法;3)所合成的多环芳烃的OFET性能的测量。
英文摘要
We have studied development of short syntheses of polycyclic aromatic hydrocarbons using coupling of aromatic ketones and arylboronates via carbon-hydrogen, carbon-oxygen, and carbon-nitrogen bond cleavages and have examined applications of these polycycl1) development of multi-arylation of acetophenones via unreactive carbon bond cleavage and construction of benzene ring by transformation of acetyl groups;2) development of new methods of short synthesis of polycyclic aromatic hydrocarbons having graphene frameworks by our multi-arylation protocols;3) measurements of OFET performance of the synthesized polycyclic aromatic hydrocarbons.
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Ruthenium-catalyzed Cross-couplings of Aromatic Ketones with Organoboronates via Unreactive Carbon-heteroatom Bonds Cleavage
钌催化芳香酮与有机硼酸酯通过非反应性碳杂原子键断裂的交叉偶联
DOI:
--
发表时间:
2012
期刊:
影响因子:
--
作者:
[Y. Masubuchi, Y. Matsumiya, H. Watanabe, S. Shiromoto, M. Tsutsubuchi, and Y. Togawa, 垣内史敏]
通讯作者:
垣内史敏
DOI:
10.1021/ol301608m
发表时间:
2012-07
期刊:
Organic letters
影响因子:
5.2
作者:
[D. Matsumura;K. Kitazawa;S. Terai;Takuya Kochi;Y. Ie;Masashi Nitani;Y. Aso;F. Kakiuchi]
通讯作者:
D. Matsumura;K. Kitazawa;S. Terai;Takuya Kochi;Y. Ie;Masashi Nitani;Y. Aso;F. Kakiuchi
DOI:
10.1246/cl.2011.1018
发表时间:
2011-09
期刊:
Chemistry Letters
影响因子:
1.6
作者:
[Takuya Kochi;Aoi Tazawa;K. Honda;F. Kakiuchi]
通讯作者:
Takuya Kochi;Aoi Tazawa;K. Honda;F. Kakiuchi
Ruthenium-Catalyzed Arylation of sp3C-H Bonds in Alkyl Ethers with Triarylboroxines via Dehydroalkoxylation
钌催化烷基醚中 sp3C-H 键与三芳基环硼氧烷通过脱氢烷氧基化进行芳基化
DOI:
--
发表时间:
2011
期刊:
影响因子:
--
作者:
[Wada, Takehiko, 垣内史敏]
通讯作者:
垣内史敏
アリールボロン酸エステルを用いたルテニウム触媒による炭素―水素結合切断を経る芳香族ニトリルのアリール化反応
使用芳基硼酸酯通过钌催化碳氢键断裂进行芳香腈的芳基化反应
DOI:
--
发表时间:
2013
期刊:
影响因子:
--
作者:
[小関裕太, 河内卓彌, 垣内史敏]
通讯作者:
垣内史敏
共 30 条
Development of convenient synthesis of multi-substituted conjugated aromatic compounds by means of carbon-hydrogen and carbon-oxygen bonds cleavage
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批准号:21350056
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$12.65万
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财政年份:2009
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负责人:KAKIUCHI Fumitoshi
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依托单位:
Innovative Advanced Protocols for Constructing Carbon-Carbon Bonds via Activation of Aromatic Carbon-Hydrogen Bond
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批准号:17065016
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项目类别:Grant-in-Aid for Scientific Research on Priority Areas
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资助金额:$12.1万
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财政年份:2005
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负责人:KAKIUCHI Fumitoshi
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依托单位:
海外基金