Development of Novel Synthetic Methods of Soluble Graphene Derivatives Having Transistor Performance

我们研究了芳香酮和芳基硼酸酯通过碳氢键、碳氧键和碳氮键断裂偶联合成多环芳烃的研究进展，并考察了这些多环化合物的应用1)通过非活性碳键裂解开发苯乙酮的多芳基化反应和通过乙酰基转化构建苯环；2)开发通过我们的多芳基化协议合成具有石墨烯骨架的多环芳烃的新方法；3)合成多环芳烃的OFET性能测试。

We have studied development of short syntheses of polycyclic aromatic hydrocarbons using coupling of aromatic ketones and arylboronates via carbon-hydrogen, carbon-oxygen, and carbon-nitrogen bond cleavages and have examined applications of these polycycl1) development of multi-arylation of acetophenones via unreactive carbon bond cleavage and construction of benzene ring by transformation of acetyl groups;2) development of new methods of short synthesis of polycyclic aromatic hydrocarbons having graphene frameworks by our multi-arylation protocols;3) measurements of OFET performance of the synthesized polycyclic aromatic hydrocarbons.