Development of Novel Synthetic Methods of Soluble Graphene Derivatives Having Transistor Performance

我们研究了芳香酮和芳基硼酸酯通过碳-氢、碳-氧和碳-氮键断裂偶联合成多环芳烃的进展，并考察了这些多环芳烃的应用：1）通过非活性碳键断裂的苯乙酮多芳基化和通过乙酰基转化的苯环结构的发展; 2）通过我们的多芳基化方案开发了具有石墨烯框架的多环芳烃的短合成的新方法;3）所合成的多环芳烃的OFET性能的测量。

We have studied development of short syntheses of polycyclic aromatic hydrocarbons using coupling of aromatic ketones and arylboronates via carbon-hydrogen, carbon-oxygen, and carbon-nitrogen bond cleavages and have examined applications of these polycycl1) development of multi-arylation of acetophenones via unreactive carbon bond cleavage and construction of benzene ring by transformation of acetyl groups;2) development of new methods of short synthesis of polycyclic aromatic hydrocarbons having graphene frameworks by our multi-arylation protocols;3) measurements of OFET performance of the synthesized polycyclic aromatic hydrocarbons.