SFB 583: Redox-Active Metal Complexes: Control of Reactivity via Molecular Architecture

SFB 583：氧化还原活性金属配合物：通过分子结构控制反应性

• 批准号: 5484668
• 金额: --
• 依托单位: Friedrich-Alexander-Universität Erlangen-Nürnberg
• 依托单位国家: 德国
• 项目类别: Collaborative Research Centres
• 财政年份: 2001
• 资助国家: 德国
• 起止时间: 2000-12-31 至 2011-12-31
• 项目状态: 已结题
• 来源: https://gepris.dfg.de/gepris/projekt/5484668?language=en
• 关键词: SFB; 583; Redox; Active; Metal

Redox reactions are a universal type of chemical reactions. Redox active metal complexes are indispensable for the majority of these reactions. The goal of this collaborative research centre is the systematic elucidation of important elementary reactions and their control via the structure of the participating metal complexes. The research projects are divided into three areas: Molecular architectures for molecule activation, Molecular architectures for charge transfer, Physical and theoretical quantification of functionality. As a first step, catalyst architectures that are able to coordinate and activate small inert molecules (N2, H2, CO, CH4, etc.) and are in turn capable of transferring electric charge will be developed. Studies on chemical reactivity, kinetic mechanistic investigations and physical measurements will elucidate quantitatively the extent of molecule activation and the amount of charge-transfer. Quantum mechanical calculations will provide microscopic details that will lead to the construction of better molecular architectures and catalytic metal complexes.

氧化还原反应是化学反应的一种普遍类型。氧化还原活性金属络合物对于大多数这些反应是必不可少的。该合作研究中心的目标是通过参与金属络合物的结构系统地阐明重要的基元反应及其控制。研究项目分为三个领域：分子活化的分子结构，电荷转移的分子结构，功能的物理和理论量化。作为第一步，能够配位和活化小的惰性分子（N2、H2、CO、CH4等）的催化剂结构被引入到催化剂体系中。并且反过来能够转移电荷。化学反应性、动力学机理研究和物理测量的研究将定量地阐明分子活化的程度和电荷转移的量。量子力学计算将提供微观细节，这将导致更好的分子结构和催化金属络合物的建设。