錯体ナノ空間が可能にする窒素含有ラダー高分子の精密合成と機能開拓

本研究计划旨在探讨配位纳米通道内氮掺杂共轭梯形聚合物（LP）的合成及其潜在应用。氮掺杂共轭液晶由于其扩展的共轭和掺杂结构而有望表现出良好的光学和电子性质。然而，使用传统方法合成的LP不可避免地遭受缺陷，例如交联和单链键，限制了它们的适用性。在这项研究中，我建议使用金属有机框架（MOFs）在配位纳米通道内合成无缺陷的LP。封闭的纳米通道可以阻止链间的相互作用，促进聚合物链的延伸，促进长共轭无缺陷的LP的形成。在合成LP后，我还将探索使用深共熔溶剂（DES）溶解和处理它们的方法。基于溶解，我将研究无缺陷的LP的物理性质，并探索它们在器件制造中的潜力。

This research proposal aims to explore the synthesis and potential applications of nitrogen-doped conjugated ladder polymers (LPs) within coordination nanochannels. Nitrogen-doped conjugated LPs are anticipated to exhibit promising optical and electronic properties due to their extended conjugated and doped structures. However, LPs synthesized using traditional methods inevitably suffer from defects, such as crosslinking and single-stranded bonds, limiting their applicability. In this study, I propose to synthesize defect-free LPs within coordination nanochannels using Metal-Organic Frameworks (MOFs). The confined nanochannels could prevent interchain interaction and facilitate the extension of polymer chains promoting the formation of long conjugated defect-free LPs. After the synthesis of LPs, I will also explore methods for solubilizing and processing them using deep eutectic solvent (DES). Based on the dissolution, I will investigate the physical properties of the defect-free LPs and explore their potential in device fabrication.