錯体ナノ空間が可能にする窒素含有ラダー高分子の精密合成と機能開拓

本研究旨在探索含氮共轭梯形聚合物(LP)在配位纳米通道中的合成及其潜在应用。氮掺杂共轭LP由于具有广泛的共轭和掺杂结构，有望表现出良好的光学和电学性质。然而，用传统方法合成的脂多糖不可避免地存在着交联性和单链键等缺陷，限制了其适用性。在这项研究中，我建议使用金属-有机骨架(MOF)在配位纳米通道内合成无缺陷的LP。受限的纳米通道可以阻止链间相互作用，促进聚合物链的延伸，促进长共轭无缺陷LP的形成。在合成了脂多糖之后，我还将探索用深共晶溶剂(DES)溶解和加工它们的方法。在溶解的基础上，我将研究无缺陷LP的物理性质，并探索其在器件制造中的潜力。

This research proposal aims to explore the synthesis and potential applications of nitrogen-doped conjugated ladder polymers (LPs) within coordination nanochannels. Nitrogen-doped conjugated LPs are anticipated to exhibit promising optical and electronic properties due to their extended conjugated and doped structures. However, LPs synthesized using traditional methods inevitably suffer from defects, such as crosslinking and single-stranded bonds, limiting their applicability. In this study, I propose to synthesize defect-free LPs within coordination nanochannels using Metal-Organic Frameworks (MOFs). The confined nanochannels could prevent interchain interaction and facilitate the extension of polymer chains promoting the formation of long conjugated defect-free LPs. After the synthesis of LPs, I will also explore methods for solubilizing and processing them using deep eutectic solvent (DES). Based on the dissolution, I will investigate the physical properties of the defect-free LPs and explore their potential in device fabrication.