錯体ナノ空間が可能にする窒素含有ラダー高分子の精密合成と機能開拓

本课题旨在探索氮掺杂共轭阶梯聚合物（lp）在配位纳米通道中的合成及其潜在应用。氮掺杂共轭lp由于其扩展的共轭和掺杂结构，预计将表现出有前途的光学和电子性能。然而，传统方法合成的LPs不可避免地存在交联、单链键等缺陷，限制了其适用性。在这项研究中，我提出在配位纳米通道中使用金属有机框架（mof）合成无缺陷的lp。受限制的纳米通道可以防止链间相互作用，促进聚合物链的延伸，促进长共轭无缺陷LPs的形成。在合成LPs后，我还将探索用深度共晶溶剂（DES）对其进行增溶和加工的方法。基于溶解，我将研究无缺陷lp的物理性质，并探索其在器件制造中的潜力。

This research proposal aims to explore the synthesis and potential applications of nitrogen-doped conjugated ladder polymers (LPs) within coordination nanochannels. Nitrogen-doped conjugated LPs are anticipated to exhibit promising optical and electronic properties due to their extended conjugated and doped structures. However, LPs synthesized using traditional methods inevitably suffer from defects, such as crosslinking and single-stranded bonds, limiting their applicability. In this study, I propose to synthesize defect-free LPs within coordination nanochannels using Metal-Organic Frameworks (MOFs). The confined nanochannels could prevent interchain interaction and facilitate the extension of polymer chains promoting the formation of long conjugated defect-free LPs. After the synthesis of LPs, I will also explore methods for solubilizing and processing them using deep eutectic solvent (DES). Based on the dissolution, I will investigate the physical properties of the defect-free LPs and explore their potential in device fabrication.