Hetero-Metallic Metal-Organic Frameworks for Photoreduction of CO2 to C2+ Hydrocarbons

用于将 CO2 光还原为 C2 碳氢化合物的异质金属金属有机框架

• 批准号: EP/Y023463/1
• 负责人: Shan Dai
• 金额: $ 25.55万
• 依托单位: University of Manchester
• 依托单位国家: 英国
• 项目类别: Fellowship
• 财政年份: 2023
• 资助国家: 英国
• 起止时间: 2023 至 无数据
• 项目状态: 未结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FY023463%2F1
• 关键词: Hetero; Metallic; Metal; Organic; Frameworks

In this project, we will be focusing on the efficient visible-light-driven photoreduction of CO2 to produce high-value-added C2+products rather than intensively reported C1 ones, which will hopefully eliminate the impact of the massive global CO2 emission andproduce valuable hydrocarbons. Transition metals, such as Cu, Fe, Ni, and Co, will be incorporated into the structure of Ti(IV)-MOFs(Metal-organic Frameworks). We will evaluate the catalytic performance of the prepared catalysts to target C2+ hydrocarbonproducts. Full characterization, including X-ray absorption near edge structure (XANES), inelastic neutron scattering (INS), pairdistribution function (PDF), and electro-optics spectroscopies will be applied to analyze the spatial distribution and electron transferprocess of the catalysts. The optimized catalysts will be scaled up and performance evaluated in large-scale reactions.

在这个项目中，我们将专注于有效的可见光驱动的二氧化碳光还原，以生产高附加值的C2+产品，而不是广泛报道的C1产品，这将有望消除全球大量二氧化碳排放的影响并生产有价值的碳氢化合物。过渡金属，如 Cu、Fe、Ni 和 Co，将被纳入 Ti(IV)-MOF（金属有机框架）的结构中。我们将评估所制备的催化剂对目标C2+烃产品的催化性能。全面的表征，包括X射线吸收近边结构（XANES）、非弹性中子散射（INS）、对分布函数（PDF）和电光光谱将用于分析催化剂的空间分布和电子转移过程。优化后的催化剂将在大规模反应中进行放大和性能评估。