International Joint Study on Complex-Based Magnetic Materials

分子磁性的领域在过去十年和几种不同的方法中表现出了明显的光谱进步，目前被用于分子基磁性的合成。我们通过两种建筑锁的用途，一种含有潜在桥接设备和其他潜在协调网站的建筑块方法被重点关注。这一方法是非常有效和成功的，可以通过选择正确的建筑块来控制多维度扩展结构和磁性属性。The Reaction products of two building components， [MnL（HイイD22イエD2O）]ClOイD24イエD2 and [Fe（CN）イD26イエD2]イD13-イD1，productes a variety of the extended multi-dimensional structures including 1D， 2D， 3D and discrete polynuclear structures and a variety of magnetic properties如ferromnet， ferrimagnet， and metamagnet。

The field of molecular magnetism has shown quite spectacular advances in the last decade and several different approaches are currently used for the synthesis of the molecular based magnets. We have focused on a building block method by the use of two kinds of building locks, one of them containing a potential bridging ligand and other of them potential coordination sites. This method is very effective and successful to control the multi-dimensional extended structure and the magnetic property by choosing proper building blocks. The reaction products of two building components, [MnL(HィイD22ィエD2O)]ClOィイD24ィエD2 and [Fe(CN)ィイD26ィエD2]ィイD13-ィエD1, produces a variety of the extended multi-dimensional structures including 1D, 2D, 3D and discrete polynuclear structures and a variety of magnetic properties such as ferromagnet, ferrimagnet, and metamagnet.