International Joint Study on Complex-Based Magnetic Materials

复杂磁性材料国际联合研究

• 批准号: 10044089
• 负责人: MATSUMOTO Naohide
• 金额: $ 3.84万
• 依托单位: Kumamoto University
• 依托单位国家: 日本
• 项目类别: Grant-in-Aid for Scientific Research (B).
• 财政年份: 1998
• 资助国家: 日本
• 起止时间: 1998 至 1999
• 项目状态: 已结题
• 来源: https://kaken.nii.ac.jp/grant/KAKENHI-PROJECT-10044089/
• 关键词: complex; magnet; blocking method; ferromagnet; spin; multi-dimensional; 磁性; 多次元構造; 結晶; 集合体; 金属

The field of molecular magnetism has shown quite spectacular advances in the last decade and several different approaches are currently used for the synthesis of the molecular based magnets. We have focused on a building block method by the use of two kinds of building locks, one of them containing a potential bridging ligand and other of them potential coordination sites. This method is very effective and successful to control the multi-dimensional extended structure and the magnetic property by choosing proper building blocks. The reaction products of two building components, [MnL(HィイD22ィエD2O)]ClOィイD24ィエD2 and [Fe(CN)ィイD26ィエD2]ィイD13-ィエD1, produces a variety of the extended multi-dimensional structures including 1D, 2D, 3D and discrete polynuclear structures and a variety of magnetic properties such as ferromagnet, ferrimagnet, and metamagnet.

在过去的十年里，分子磁学领域取得了令人瞩目的进展，目前有几种不同的方法被用于合成分子基磁体。我们重点研究了两种构建锁的构建方法，其中一种构建锁包含潜在的桥联配体，另一种构建锁包含潜在的配位位点。这种方法通过选择合适的积木块来控制多维扩展结构和磁性是非常有效和成功的。两个建筑组分[MnL(HィイD22ィエD2O)]ClOィイD24ィエD2和[Fe(CN)ィイD26ィエD2]ィイD13-ィエD1的反应产物产生了各种扩展的多维结构，包括一维、二维、三维和离散多核结构以及各种磁性，如铁磁、亚铁磁体和偏磁体。

项目成果

H. Miyasaka, H. Ieda, N. Matsumoto, N. Re, R. Crescenzi, and C. Floriani: "Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures using a Desolvation Reaction: Synthesis, Structure, and Magnetic Properties of Manganese(III)-Schiff-Base-H

H. Miyasaka、H. Ieda、N. Matsumoto、N. Re、R. Crescenzi 和 C. Floriani：“使用去溶剂化反应将双核、三核和五核配合物组装成扩展结构：合成、结构和磁性

宮坂,松本,C.フロリマーニ他: "マンガン(III)シッフ塩基と[Fe(CN)_6]^<3->反応による集積錯体" Inorganic Chemistry. 37・2. 255-263 (1998)

Miyasaka、Matsumoto、C. Florimani 等人：“通过与锰(III)席夫碱和[Fe(CN)_6]^<3->反应形成的复合物”无机化学37・2 (1998)。

砂月他: "Synthesis, Magnetic properties, and Incomplete Double-Cu base Structure of Mn(III)-M(II) Complexes"Inorganic Chemistry. 37. 5566-5574 (1998)

Sunazuki 等人：“Mn(III)-M(II) 配合物的合成、磁性和不完整双 Cu 基结构”无机化学 37. 5566-5574 (1998)

砂月他: "Synthesis, Magnetic Properties, and Incomplete Double-cubare structure of Mn(III)-M(II) Complexes"Inorganic Chemistry. 37. 5566-5574 (1998)

Sunazuki 等：“Mn(III)-M(II) 配合物的合成、磁性和不完整双立方结构”无机化学 37. 5566-5574 (1998)

椎他: "Deprotonation-induced Enantioselective Aggregation and Deprotonation-induced Ligand Reamanagement of Copper(II)"Inorganic Chemistry. 38. 3513-3522 (1999)

Shii 等人：“铜 (II) 的去质子化诱导的对映选择性聚集和去质子化诱导的配体重新管理”无机化学 38. 3513-3522 (1999)