Tailoring multifunctional single site catalysts for carbon dioxide conversion

定制用于二氧化碳转化的多功能单中心催化剂

• 批准号: DE190101618
• 负责人: Dr Zichun Wang
• 金额: $ 27.28万
• 依托单位: Macquarie University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Early Career Researcher Award
• 财政年份: 2019
• 资助国家: 澳大利亚
• 起止时间: 2019-01-01 至 2022-06-30
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DE190101618
• 关键词: Tailoring; multifunctional; single; site; catalysts

This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental benefits. The project is expected to advance the knowledge in rational design of new catalysts for CO2 conversion and understanding the catalyst structure-property induced reaction mechanism. This will result in an improved understanding of the reaction kinetics of utilising CO2 as a feedstock.

该项目旨在开发多功能单活性中心催化剂和协同表面活性中心，以完成二氧化碳加氢制高级醇的多步反应，并提高对大链醇的选择性。CO2是一种丰富的可再生碳源，可用作原料，以节能方式关闭碳循环具有显著的环境效益。该项目有望在合理设计用于CO2转化的新型催化剂和理解催化剂结构-性能诱导的反应机理方面取得进展。这将导致对利用CO2作为原料的反应动力学的更好理解。