Novel organic architectures and functional materials from tropylium ions

来自鎓离子的新型有机结构和功能材料

• 批准号: FT180100260
• 负责人: A/Prof Thanh Vinh Nguyen
• 金额: $ 51.79万
• 依托单位: The University of New South Wales
• 依托单位国家: 澳大利亚
• 项目类别: ARC Future Fellowships
• 财政年份: 2019
• 资助国家: 澳大利亚
• 起止时间: 2019-01-01 至 2022-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/FT180100260
• 关键词: Novel; organic; architectures; functional; materials

This project aims to develop new synthetic applications of tropylium ions, as versatile building blocks, to access a broad range of organic structures that used to be difficult and problematic to synthesise. The non-benzenoid aromatic tropylium ion exhibits a unique combination of structural stability and chemical reactivity. This project expects to use tropylium ions as chromophores to derive novel ‘push-and-pull’ organic dyes with highly applicable physicochemical properties.This will provide access to a family of novel complex organic structures in a new chemical space, as well as new materials for opto-electronic and sensing applications, respectively.

该项目旨在开发托吡酯离子的新的合成应用，作为多功能的构建模块，以获得广泛的有机结构，这些结构过去很难合成。非苯型芳族托吡酯离子表现出结构稳定性和化学反应性的独特组合。本项目将利用托吡酯离子作为发色团，衍生出具有高度适用的物理化学性质的新型“推拉”有机染料，这将为在新的化学空间中获得一系列新型复杂有机结构，以及分别用于光电和传感应用的新材料提供途径。