Charging transition metals with activating alkanes

用活化烷烃对过渡金属充电

• 批准号: DP170104301
• 负责人: A/Prof Graham Ball
• 金额: $ 19.98万
• 依托单位: The University of New South Wales
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2017
• 资助国家: 澳大利亚
• 起止时间: 2017-01-01 至 2023-06-30
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP170104301
• 关键词: Charging; transition; metals; activating; alkanes

The project aims to engineer positively charged metal complexes and use them to explore the chemistry of bound activated alkane ligands. The transformation of cheap, plentiful alkanes into more valuable products is a major quest in chemistry, and complexes of alkanes bound to metals are expected to play a key role in transformations of alkanes. The project intends to use the activated metal bound alkane to transform the normally inert alkane into compounds with desirable functional groups. This should make the synthesis of alkane complexes stable at room temperature in solution a realistic possibility. These cheap, plentiful alkanes can be turned into more valuable products, bringing benefits to industry.

该项目旨在设计带正电荷的金属络合物，并使用它们来探索结合活化的烷烃配体的化学反应。廉价，丰富的烷烃转化为更有价值的产品是化学方面的主要追求，预计与金属的烷烃的复合物有望在烷烃的转化中起关键作用。该项目打算使用激活的金属结合的烷烃将正常惰性烷烃转化为具有理想官能团的化合物。这应该使烷基复合物的合成在室温下在溶液中稳定成为现实的可能性。这些廉价，丰富的烷烃可以变成更有价值的产品，从而为工业带来好处。