SYNTHETIC AND PHYSICAL STUDIES OF ANTICANCER AGENTS

五配位硫物种的合成已扩展到硫烷 亚胺类。我们将探索这些新物种的化学成分。更简单 将寻找五价碳物种的例子。AN的合成 具有桥硫原子的邻位桥联三芳基醇将使用新的 芳香磺酸直接邻位锂化合成方法学 酸。

Syntheses of pentacoordinate sulfure species have been extended to sulfurane imines. The chemistry of these novel species will be explored. Simpler examples of pentavalent carbon species will be sought. The synthesis of an ortho-bridged triarylcarbinol with bridge sulfur atoms will be pursued using new synthetic methodology involving the directed ortho-lithiation of arenesulfonic acids.