Cobalt- and Nickel-based Polymetallocenes: Functional Metallopolymers from Earth-Abundant Metals

钴基和镍基多茂金属：来自地球丰富金属的功能性金属聚合物

• 批准号: EP/N030702/1
• 负责人: Ian Manners
• 金额: $ 33.6万
• 依托单位: University of Bristol
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2016
• 资助国家: 英国
• 起止时间: 2016 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FN030702%2F1
• 关键词: Cobalt; Nickel; based; Polymetallocenes; Functional

The field of polymers containing metal atoms as part of the structure (metallopolymers) is relatively new in comparison to that of polymers in general. Nevertheless, recent advances in this area have established metallopolymers as an attractive class of easily processed materials in which metal centres introduce properties and functions that complement those available with state-of-the-art organic macromolecules. This proposal outlines a research programme to synthetically develop and to understand the properties of two new classes of metallopolymers based on the metals cobalt and nickel, and also to lay the foundations for their exploitation, with a particular focus on their antimicrobial and magnetic properties. The development of new antibiotics is of key global importance due to the reduced effectiveness of currently available compounds towards infection. In addition, the development of easily processed polymeric materials that function as magnets is particularly desirable for a range of applications in computers and other devices.

与一般聚合物相比，含有金属原子作为结构一部分的聚合物（金属聚合物）领域相对较新。然而，该领域的最新进展已使金属聚合物成为一类有吸引力的易于加工的材料，其中金属中心引入的性能和功能补充了最先进的有机大分子的性能和功能。该提案概述了一项研究计划，旨在综合开发和了解基于金属钴和镍的两类新型金属聚合物的特性，并为它们的开发奠定基础，特别关注它们的抗菌和磁性。由于现有化合物对抗感染的有效性降低，新抗生素的开发具有全球重要性。此外，开发易于加工的磁体聚合物材料对于计算机和其他设备中的一系列应用来说是特别理想的。

项目成果

Redox Chemistry of Nickelocene-Based Monomers and Polymers

茂镍基单体和聚合物的氧化还原化学

• DOI: 10.1021/acs.organomet.1c00247
• 发表时间: 2021
• 期刊: Organometallics
• 影响因子: 2.8
• 作者: Musgrave R

Main-chain metallopolymers at the static-dynamic boundary based on nickelocene

• DOI: 10.1038/nchem.2743
• 发表时间: 2017-08-01
• 期刊: NATURE CHEMISTRY
• 影响因子: 21.8
• 作者: Musgrave, Rebecca A.;Russell, Andrew D.;Manners, Ian
• 通讯作者: Manners, Ian

Role of torsional strain in the ring-opening polymerisation of low strain [n]nickelocenophanes.

扭转应变在低应变[n]二茂镍开环聚合中的作用。

• DOI: 10.1039/c9sc02624j
• 发表时间: 2019
• 期刊: Chemical science
• 影响因子: 8.4
• 作者: Musgrave RA