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The synthesis, design and characterization of new porous liquids with analysis for the direct aim of industrial applications

新型多孔液体的合成、设计和表征以及针对工业应用的直接目标的分析

基本信息

批准号：
1786239
负责人：
金额：
--
依托单位：
Queen's University Belfast
依托单位国家：
英国
项目类别：
Studentship
财政年份：
2016
资助国家：
英国
起止时间：
2016 至无数据
项目状态：
已结题

来源：
https://gtr.ukri.org/projects?ref=studentship-1786239
关键词：
synthesis design characterization new porous

项目摘要

The project is based in the area of inorganic chemistry with the use of metals (both transition metals and non-transition metals) with coordinating organic components to create a new type of liquid material known as a porous liquid. The porous liquid will be synthesized by various means including mechanochemically and via solution based methods. There will be an evaluation of each type of synthesis and potentially further investigation into the synthesis of porous liquids on a large/industrial scale.Components used to make the porous liquid can vary and each will be analysed and their different properties recorded. The aim in creating this class of material is to successfully and easily synthesize the material while being cost effective and having a degree of variation to meet different specification.Characterization will involve analytical techniques such as infrared spectroscopy, thermogravimetric analysis, powder X-ray diffraction and Brunauer-Emmett-Teller surface area analysis to determine if the porous liquids that are synthesized are in accordance with similar data produced from various components.The porous liquids will be subjected to Karl Fischer analysis to measure water uptake and will be analysed for their ability to absorb a range of different guests. This will determine their possible application in the industry.The new material will be analysed for its capability to retain and desorb guests as well as regenerate porosity. Kinetic studies will also be carried out to determine how effective the liquid is at absorbing the different guests it will be subject too.Further work will include the use of mechanochemistry to investigate more into porous liquids with the aim of increased stability and functionality. Functionalized porous liquids can be foreseen to have the properties of luminescence and 'flexibility'. With these functionalized porous liquids, many possible applications can be foreseen in industrial settings.

该项目基于无机化学领域，使用金属（过渡金属和非过渡金属）与配位有机成分，以创造一种称为多孔液体的新型液体材料。多孔液体将通过各种手段合成，包括机械化学和经由基于溶液的方法。将对每种类型的合成进行评估，并可能对大规模/工业规模的多孔液体合成进行进一步研究。用于制造多孔液体的成分可能不同，每种成分都将被分析，并记录其不同的性质。创造这类材料的目的是成功和容易地合成材料，同时具有成本效益，并具有一定程度的变化，以满足不同的规格。表征将涉及分析技术，如红外光谱，热重分析，粉末X射线衍射和Brunauer-Emmett-泰勒表面积分析，以确定所合成的多孔液体是否与由各种组分产生的类似数据一致。卡尔费休分析，以测量吸水率，并将分析其吸收一系列不同客人的能力。这将决定它们在工业上的可能应用。新材料将被分析其保留和解吸客人以及再生孔隙的能力。动力学研究也将进行，以确定如何有效的液体是在吸收不同的客人，它也将是主题。进一步的工作将包括使用机械化学研究更多的多孔液体，目的是增加稳定性和功能。功能化多孔液体具有发光和“柔性”的特性。利用这些功能化多孔液体，可以预见在工业环境中的许多可能的应用。