Low oxidation state magnesium complexes: multitalented reagents for sustainable chemical synthesis

低氧化态镁配合物：用于可持续化学合成的多功能试剂

• 批准号: DP140101926
• 负责人: Prof Cameron Jones
• 金额: $ 31.45万
• 依托单位: Monash University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2014
• 资助国家: 澳大利亚
• 起止时间: 2014-01-01 至 2017-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP140101926
• 关键词: Low; oxidation; state; magnesium; complexes

The chemistry of stable low oxidation state s-block compounds was initiated at Monash in 2007. In addition to being of major fundamental importance, applications of these highly reactive systems have rapidly developed. To cement Australia's international lead in this emerging and competitive field, this project aims to develop a new generation of magnesium(I) (and related) compounds, and to install them as sought after reagents for sustainable synthetic methodologies. For the first time, environmentally benign s-block compounds will be utilised for the low energy stoichiometric and catalytic transformation of abundant, often inert gaseous small molecules, for example, hydrogen, nitrogen, carbon dioxide, carbon monoxide, to value added products important to industry and academia.

稳定的低氧化态S嵌段化合物的化学于2007年在莫纳什启动。除了具有重要的基础性意义外，这些高活性体系的应用也得到了迅速发展。为了巩固澳大利亚在这个新兴和竞争激烈的领域的国际领先地位，该项目旨在开发新一代镁(I)(和相关)化合物，并将它们安装为可持续合成方法的热门试剂。环境友好的S嵌段化合物将首次被用于低能量化学计量比和催化转化丰富的、通常是惰性的气体小分子，例如氢、氮、二氧化碳、一氧化碳，以获得对工业和学术界重要的附加值产品。