Magnesium(I) complexes: Potent workhorse reagents

镁 (I) 络合物：有效的主力试剂

• 批准号: DP170104454
• 负责人: Prof Cameron Jones
• 金额: $ 38.21万
• 依托单位: Monash University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2017
• 资助国家: 澳大利亚
• 起止时间: 2017-06-01 至 2022-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP170104454
• 关键词: Magnesium; complexes; Potent; workhorse; reagents

This project aims to install magnesium(I) compounds as powerful and selective reagents to prepare metal-metal bonded compound classes that are otherwise inaccessible. These environmentally benign species will be viable alternatives to established systems, incorporating expensive and toxic metals, which are currently used for the stoichiometric/catalytic transformation of small molecules to value added products. The project is expected to cement Australia's internationally leading role in the emerging field of low oxidation state s-block chemistry. The development and commercialisation of magnesium(I), and related compounds as reagents for the selective synthesis of value added products will provide significant economic benefits to fine chemicals industries.

该项目旨在将镁（I）化合物作为强大的选择性试剂，用于制备其他方法无法获得的金属-金属键合化合物。这些对环境无害的物种将是现有系统的可行替代品，这些系统包含昂贵和有毒的金属，目前用于将小分子化学计量/催化转化为增值产品。该项目预计将巩固澳大利亚在低氧化态S区化学新兴领域的国际领先地位。镁（I）和相关化合物作为选择性合成增值产品的试剂的开发和商业化将为精细化学品工业提供显著的经济效益。