Reactivity Enhanced Low-Valent Alkaline Earth Metal Compounds

反应活性增强的低价碱土金属化合物

• 批准号: DP240101097
• 负责人: Prof Cameron Jones
• 金额: $ 37.4万
• 依托单位: Monash University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2024
• 资助国家: 澳大利亚
• 起止时间: 2024-01-01 至 2026-12-31
• 项目状态: 未结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP240101097
• 关键词: Reactivity; Enhanced; Low; Valent; Alkaline

The project aims to develop highly activated low oxidation state alkaline earth metal complexes as cheap and sustainable alternatives to toxic/expensive late transition metal complexes, that currently dominate the transformation of inert small molecule substrates into value-added organic chemicals. The project expects to generate major fundamental and applied advances in chemistry, using innovative synthetic and computational approaches, and a multidisciplinary collaborative team. Expected outcomes include building of academic and, later, industrial research capacity, knowledge, an international network, and a highly trained workforce. Success should see substantial economic, environmental and societal benefits flowing to Australia.

该项目旨在开发高活性、低氧化态的碱土金属络合物，作为有毒/昂贵的后过渡金属络合物的廉价和可持续的替代品，后者目前主导着惰性小分子底物向增值有机化学品的转化。该项目预计将利用创新的合成和计算方法以及一个多学科合作团队，在化学领域产生重大的基础和应用进展。预期成果包括建设学术和后来的工业研究能力、知识、国际网络和训练有素的劳动力。成功应该会给澳大利亚带来巨大的经济、环境和社会效益。