Mixed-Metal Clusters for Catalysis and Optical Applications

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This project aims to afford new heterometallic molecular materials as precursors to catalysts and as new optical materials, exploiting oxophilic and carbophilic transition metal atoms for synergistic cooperation in certain catalytic processes, and using the polarity of heterometallic bonds to achieve strong optical limiting. Expected outcomes of this project include cluster structure/composition - catalysis/optical properties correlations that will signpost the route to efficient catalysts and optical limiters. This Project should provide significant benefits such as chemoselective catalysts needed for pharmaceutical drug and agricultural chemical production, and broad temporal range optical limiters needed for optical device protection.