Multifunctional metal alkynyls for nonlinear optics.

用于非线性光学的多功能炔基金属。

• 批准号: DP140102219
• 负责人: Prof Mark Humphrey
• 金额: $ 39.11万
• 依托单位: The Australian National University
• 依托单位国家: 澳大利亚
• 项目类别: Discovery Projects
• 财政年份: 2014
• 资助国家: 澳大利亚
• 起止时间: 2014-01-01 至 2016-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/DP140102219
• 关键词: Multifunctional; metal; alkynyls; nonlinear; optics.

Developments in photonics necessitate materials with enhanced, tunable, and/or reversibly switchable nonlinear optical properties that can be used to control or process incident light beams. This project will explore new possibilities: to maximise molecular NLO properties while enhancing modulation and switching; multipolar metal alkynyl complexes will be targeted, building systematically on our preliminary results; organometallic alkynyl units will be hybridised with functional organic and coordination complex modules to develop novel multifunctional systems; and, supported nanoarchitectures will be constructed to demonstrate practical NLO switching, with potential applications in photonics technologies.

光子学的发展需要具有增强、可调谐和/或可逆切换非线性光学特性的材料，这些材料可用于控制或处理入射光束。该项目将探索新的可能性：最大化分子NLO特性，同时增强调制和开关；多极金属炔基配合物将有针对性，系统地建立在我们的初步结果；有机金属炔基单元将与功能有机和配位复合模块杂交，发展新型多功能体系；并且，支持的纳米架构将被构建来演示实际的NLO开关，并在光子学技术中具有潜在的应用。