Modulated Self-Assembly of p-Block Metal-Organic Frameworks

p-嵌段金属有机框架的调制自组装

• 批准号: 2748977
• 金额: --
• 依托单位: University of Glasgow
• 依托单位国家: 英国
• 项目类别: Studentship
• 财政年份: 2022
• 资助国家: 英国
• 起止时间: 2022 至 无数据
• 项目状态: 未结题
• 来源: https://gtr.ukri.org/projects?ref=studentship-2748977
• 关键词: Modulated; Self; Assembly; Block; Metal

Our group has a track record in the development of modulated self-assembly protocols for metal-organic frameworks (MOFs), using additives and fine control of synthetic conditions to tune phase formation, defectivity, particle size, surface chemistry, porosity, etc (see perspective: Chem. Sci. 2020, 11, 4546-4562). The majority of our work to date has focused on d- and f- block MOFs; this project will extend and develop new protocols for the synthesis and discovery of MOFs linked by p-block elements, specifically those in group 13 (Al, Ga, In). The new materials discovered in this project will feed into existing projects covering gas storage of flexible materials, characterization of optical and mechanical properties, novel reactivities

我们的团队在开发金属有机框架（mof）的调制自组装协议方面有着良好的记录，使用添加剂和精细控制合成条件来调整相形成，缺陷，粒度，表面化学，孔隙率等（参见视角：化学）。自然科学学报，2020,11(4):446 - 462。迄今为止，我们的大部分工作都集中在d块和f块mof上；该项目将扩展和开发新的方案，以合成和发现由p块元素连接的mof，特别是那些在13族（Al, Ga, in）。在这个项目中发现的新材料将为现有的项目提供支持，包括柔性材料的储气、光学和机械性能的表征、新型反应性