Synthesis beyond the redox-active tetrathiafulvalene (TTF) molecule: From a topological control in TTF-based macrocycles, towards functional s

氧化还原活性四硫富瓦烯 (TTF) 分子之外的合成：从基于 TTF 的大环化合物的拓扑控制到功能性化合物

• 批准号: EP/E041337/1
• 负责人: Peter Skabara
• 金额: $ 3.79万
• 依托单位: University of Strathclyde
• 依托单位国家: 英国
• 项目类别: Research Grant
• 财政年份: 2007
• 资助国家: 英国
• 起止时间: 2007 至 无数据
• 项目状态: 已结题
• 来源: https://gtr.ukri.org/projects?ref=EP%2FE041337%2F1
• 关键词: Synthesis; beyond; redox; active; tetrathiafulvalene

Functionalised TTFs are pi-electron rich redox-active building blocks which, quite importantly, are stable to many synthetic transformations. In fact, a great variety of applications can be associated with the TTF systems, ranging from solid state electroconducting and magnetic properties of molecular organic metals to molecular/supramolecular systems involving reversible redox, intermolecular charge-transfer and hydrogen-bonding properties of TTF derivatives. This application supports the activities of a COST D31 network by providing funding for travel, consumables and subsistence for visits from four of the COST partners. The aims of the research projects presented here entertain a general theme for incorporating TTF species into thiophene based molecules and macromolecules. The target materials are potential components in electronic devices, such as field effect transistors, magnets and photovoltaics.

功能化的TTF是富含pi电子的氧化还原活性积木，非常重要的是，它对许多合成转化都是稳定的。事实上，TTF体系具有广泛的应用，从分子有机金属的固态导电和磁性，到涉及TTF衍生物的可逆氧化还原、分子间电荷转移和氢键性质的分子/超分子体系。该应用程序通过为四个成本伙伴的访问提供旅费、消耗品和生活费来支持成本D31网络的活动。这里提出的研究项目的目的是为了将TTF物种合并到基于噻吩基的分子和大分子中。目标材料是电子设备中的潜在元件，如场效应晶体管、磁铁和光伏。

项目成果

The Introduction of Pyrrolotetrathiafulvalene into Conjugated Architectures: Synthesis and Electronic Properties

将吡咯四硫富瓦烯引入共轭结构：合成和电子特性

• DOI: 10.1002/marc.200800154
• 发表时间: 2008
• 期刊: Macromolecular Rapid Communications
• 影响因子: 4.6
• 作者: Kanibolotsky A