Nanocrystal and crystal structure determination by novel x-ray methods

通过新型 X 射线方法测定纳米晶体和晶体结构

• 批准号: 298551-2007
• 负责人: Kycia, Stefan
• 金额: $ 3.92万
• 依托单位: University of Guelph
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2008
• 资助国家: 加拿大
• 起止时间: 2008-01-01 至 2009-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=396181
• 关键词: Nanocrystal; crystal; structure; determination; novel

The determination of crystalline structure has traditionally been accomplished by means of single crystal and polycrystalline x-ray diffraction techniques. Both have been developed extensively and have had great success over the years. Nanoscience has presented several fundamental problems that cannot be solved by current techniques of any kind, therefore hindering the progress in the understanding of basic issues. For instance, what is the atomic arrangement and composition of a nanocrystal? New, 'non-traditional' x-ray scattering methods must be developed in order to answer these questions. My group intends to resolve fine details of the atomic structure of free nanoparticles of gold and silver as well as binary alloys. These studies will be performed by high energy x-ray diffraction, (high resolution radial distribution method) and by anomalous x-ray diffraction method. These are methods that we have been developing over the years to allow the atomic resolution of nanoparticles. We will continue to study the chemical composition, strain and elastic energy of self-assembled islands and other epitaxial systems by means of grazing incidence x-ray diffraction. The group will also develop powder diffraction and multiple beam diffraction for ab-initio structure determination of systems ranging from quasicrystals to protein crystals.

晶体结构的测定传统上是通过单晶和多晶X射线衍射技术来完成的。这两种方法都得到了广泛的发展，多年来取得了巨大的成功。纳米科学提出了一些根本性的问题，这些问题无法通过现有的任何技术来解决，因此阻碍了对基本问题的理解。例如，一个原子的排列和组成是什么？新的，“非传统”的X射线散射方法必须开发，以回答这些问题。我的团队打算解决金和银以及二元合金的自由纳米粒子的原子结构的细节。这些研究将通过高能X射线衍射（高分辨率径向分布方法）和异常X射线衍射方法进行。 这些都是我们多年来一直在开发的方法，以允许纳米粒子的原子分辨率。 我们将继续研究化学成分，应变和弹性能的自组装岛和其他外延系统的掠入射x射线衍射的手段。该小组还将开发粉末衍射和多光束衍射，用于从准晶到蛋白质晶体的从头计算结构测定。