Depth resolved properties of nanoscopic heterostructures using ß-NMR

使用 NMR 深度解析纳米异质结构的特性

• 批准号: 261670-2009
• 负责人: MacFarlane, Andrew
• 金额: $ 2.19万
• 依托单位: University of British Columbia
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2010
• 资助国家: 加拿大
• 起止时间: 2010-01-01 至 2011-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=456053
• 关键词: Depth; resolved; properties; nanoscopic; heterostructures

When materials are combined, not through formation of a compound, but instead into a heterostructure (in the simplest instance, a thin film of one material on a substrate of another) the resulting properties may differ substantially from those of each of the pure bulk starting materials. Such "metamaterials" have important applications in electronics and sensors, and newly developed metamaterials can have unprecedented properties which may form the basis of entirely new technologies, such as quantum computers or spintronics. In a similar way, the properties of materials differ at a free surface, for example, in surface reconstruction, the crystal structure of atoms at the surface is different from that of a simple truncation of the bulk. Such effects can (and generally do) propagate below the surface. Thus, the properties of metamaterials and crystals near a free surface are depth dependent. Remarkably little is known about such phenomena, mainly because very few depth-resolved techniques are available. This proposal aims to use the technique of low energy beta detected nuclear magnetic resonance at TRIUMF, Canada's National Lab for Particle and Nuclear Physics, as a new depth-resolved (at the nanometer scale, i.e. one billionth of a meter) experimental probe of solid materials, addressing fundamental and practical questions in, for example, magnetism and superconductivity in nanoscopically structured metamaterials. The diffusive motion of ions in solids is another practically important property (for instance in solid state electrochemical batteries) that is modified (and depth-dependent) in the vicinity of an interface or free surface. The proposal also aims to study diffusion of the isolated probe ions in this context.

当材料不是通过形成化合物而是形成异质结构(在最简单的情况下，一种材料在另一种材料的衬底上形成薄膜)时，所产生的性能可能与每一种纯块体起始材料的性能有很大的不同。这种“超材料”在电子学和传感器中有重要的应用，而新开发的超材料可以具有前所未有的特性，这些特性可能构成全新技术的基础，如量子计算机或自旋电子学。同样，材料在自由表面的性质也不同，例如，在表面重建中，表面原子的晶体结构不同于简单的体相截断。这样的影响可以(通常也确实)在表面之下传播。因此，自由表面附近的超材料和晶体的性质与深度有关。令人惊讶的是，人们对这种现象知之甚少，主要是因为几乎没有深度分辨技术可用。这项提议旨在使用加拿大国家粒子和核物理实验室TRIUMF的低能β探测核磁共振技术，作为一种新的深度分辨(纳米尺度，即十亿分之一米)固体材料实验探测器，解决例如纳米结构超材料中的磁性和超导等基本和实际问题。离子在固体中的扩散运动是另一个实际重要的性质(例如在固态电化学电池中)，它在界面或自由表面附近被修改(和深度相关)。该提案还旨在研究孤立的探测离子在这方面的扩散。