Multiphysics of bubbles and nanoparticles in porous media: Novel approaches to the remediation of subsurface environments contaminated by chlorinated organic substances

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Soil and groundwater at abandoned industrial facilities (brown-field sites) in Canada remain contaminated by chlorinated volatile organic compounds (VOCs), long after the use of these chemicals has ceased. Chlorinated organics are denser than water, causing subsurface contamination deep below the water table. Their intermediate by-products are believed to be potent carcinogens and are thus a major threat to groundwater resources. The success of many remediation strategies is limited by the difficulty of introducing a gas phase uniformly within VOC source zones below the water table, as would be necessary for transferring a VOC into the flowing gas phase or for supplying reactive gases (e.g., oxygen, hydrogen, methane) for use by contaminant-degrading bacteria.