Structure-Reactivity Relationships for Extended Solids: Tailored Design of Highly Functional Materials

扩展固体的结构-反应性关系：高功能材料的定制设计

• 批准号: RGPIN-2014-05656
• 负责人: Bieringer, Mario
• 金额: $ 2.48万
• 依托单位: University of Manitoba
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2014
• 资助国家: 加拿大
• 起止时间: 2014-01-01 至 2015-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=567306
• 关键词: Structure; Reactivity; Relationships; Extended; Solids

Oxide based materials are very common and have played vital roles in miniaturization of technologies and have opened up avenues for higher efficiency devices. The performance of rechargeable batteries have improved significantly during the last decade and are now reliable components in all types of devices (cell phones, computers, cars, medical devices). Solid Oxide Fuel Cells (SOFC) are highly efficient secondary power sources that can tolerate diverse fuels and require almost no maintenance. At the center of most of these devices are inorganic solid state materials that need to optimized for their respective functions. There is a tremendous need for tailored materials that can provide reliable and efficient performance while being economically competitive. This proposal is concerned with these functional inorganic materials and their controlled preparation and processing. Unfortunately to date the chemical reactivity and formation of solid state materials is only very poorly understood. In fact the successful targeted preparation of a functional material often depends on the experience and intuition of synthetic chemists. Our target compounds are ceramics with applications in energy conversion, oxide ion conductors for solid oxide fuel cell (SOFC) technology and novel layered lithium conductors for rechargeable batteries. Unfortunately almost no rational design strategies for the synthesis of inorganic materials are available. The same materials composition can result in a variety of different structures with different properties, traditionally most metal oxides are prepared directly at high temperatures (T > 1000°C) while ignoring the structural and thus functional diversity accessible at lower temperatures using indirect synthetic routs. The Bieringer research group has clearly demonstrated the large number of metastable structures that are accessible at lower temperatures. We monitor solid state chemical reactions in real time and derive reaction pathways which provide structure-reactivity relationships for extended solids. At lower temperatures we have encountered diverse oxide defect structures (oxide defect structures are responsible for oxide ion conduction) with potential applications as solid state electrolytes. In this particular proposal we aim at further exploring solid state reaction pathways in an attempt to establish reliable structure-reactivity relationships which will enable the rational design of functional solid state materials. The second component of this proposal deals with low temperature topotactic reactions where we only modify parts of a structure during the reaction. We are employing metal hydrides as solid state reductants. Those permit us to prepare metastable products derived from the parent host structures and can exhibit unusual oxidation states and coordination environments. A specific application is concerned with the simultaneous reduction (topotactic oxide ion removal) and cation intercalation in layered oxide structures. These phases are potentially tunable lithium conductors for rechargeable battery technology. The proposed research program will provide unique training opportunities for students and prepares graduates for the renewable energy research environment in Canada.

氧化物材料非常常见，在技术小型化方面发挥了至关重要的作用，并为更高效率的器件开辟了道路。可充电电池的性能在过去十年中有了显著提高，现在是所有类型设备(手机、计算机、汽车、医疗设备)的可靠部件。固体氧化物燃料电池(SOFC)是一种高效的二次能源，可以承受多种燃料，几乎不需要维护。这些设备中的大多数是无机固态材料，它们需要针对各自的功能进行优化。在经济上具有竞争力的同时，对能够提供可靠和高效性能的定制材料有着巨大的需求。本提案涉及这些功能无机材料及其受控制备和加工。不幸的是，到目前为止，人们对固态材料的化学反应和形成的了解还很少。事实上，功能材料的成功靶向制备往往依赖于合成化学家的经验和直觉。我们的目标化合物是用于能量转换的陶瓷，用于固体氧化物燃料电池(SOFC)技术的氧化物离子导体，以及用于充电电池的新型层状锂导体。不幸的是，对于无机材料的合成几乎没有合理的设计策略可用。相同的材料组成可能导致各种不同的结构和不同的性质，传统上大多数金属氧化物是直接在高温(T&gT；1000°C)下制备的，而忽略了在较低温度下使用间接合成路线可以获得的结构和功能的多样性。比林格研究小组已经清楚地证明了在较低温度下可以获得大量亚稳态结构。我们实时监控固态化学反应，并导出反应路径，提供扩展固体的结构-反应性关系。在较低的温度下，我们遇到了各种各样的氧化物缺陷结构(氧化物缺陷结构负责氧化物离子传导)，作为固体电解质具有潜在的应用前景。在这个特殊的建议中，我们的目标是进一步探索固态反应途径，试图建立可靠的结构-反应关系，这将使功能固态材料的合理设计成为可能。这一建议的第二个组成部分涉及低温拓扑定向反应，在反应过程中我们只修改结构的一部分。我们使用金属氢化物作为固态还原剂。这使得我们能够制备源于母体结构的亚稳态产物，并且可以表现出不寻常的氧化状态和配位环境。一个具体的应用是关于层状氧化物结构中的同时还原(拓扑定向氧化物离子去除)和阳离子插层。这些相可能是可调节的锂导体，用于可充电电池技术。拟议的研究计划将为学生提供独特的培训机会，并使毕业生为加拿大的可再生能源研究环境做好准备。