Structure-Reactivity Relationships for Extended Solids: Tailored Design of Highly Functional Materials

扩展固体的结构-反应性关系：高功能材料的定制设计

• 批准号: RGPIN-2014-05656
• 负责人: Bieringer, Mario
• 金额: $ 2.48万
• 依托单位: University of Manitoba
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2017
• 资助国家: 加拿大
• 起止时间: 2017-01-01 至 2018-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=632338
• 关键词: Structure; Reactivity; Relationships; Extended; Solids

Oxide based materials are very common and have played vital roles in miniaturization of technologies and have opened up avenues for higher efficiency devices. The performance of rechargeable batteries have improved significantly during the last decade and are now reliable components in all types of devices (cell phones, computers, cars, medical devices). Solid Oxide Fuel Cells (SOFC) are highly efficient secondary power sources that can tolerate diverse fuels and require almost no maintenance. At the center of most of these devices are inorganic solid state materials that need to optimized for their respective functions. There is a tremendous need for tailored materials that can provide reliable and efficient performance while being economically competitive. This proposal is concerned with these functional inorganic materials and their controlled preparation and processing. Unfortunately to date the chemical reactivity and formation of solid state materials is only very poorly understood. In fact the successful targeted preparation of a functional material often depends on the experience and intuition of synthetic chemists. Our target compounds are ceramics with applications in energy conversion, oxide ion conductors for solid oxide fuel cell (SOFC) technology and novel layered lithium conductors for rechargeable batteries. Unfortunately almost no rational design strategies for the synthesis of inorganic materials are available. The same materials composition can result in a variety of different structures with different properties, traditionally most metal oxides are prepared directly at high temperatures (T > 1000°C) while ignoring the structural and thus functional diversity accessible at lower temperatures using indirect synthetic routs. The Bieringer research group has clearly demonstrated the large number of metastable structures that are accessible at lower temperatures. We monitor solid state chemical reactions in real time and derive reaction pathways which provide structure-reactivity relationships for extended solids. At lower temperatures we have encountered diverse oxide defect structures (oxide defect structures are responsible for oxide ion conduction) with potential applications as solid state electrolytes. In this particular proposal we aim at further exploring solid state reaction pathways in an attempt to establish reliable structure-reactivity relationships which will enable the rational design of functional solid state materials. The second component of this proposal deals with low temperature topotactic reactions where we only modify parts of a structure during the reaction. We are employing metal hydrides as solid state reductants. Those permit us to prepare metastable products derived from the parent host structures and can exhibit unusual oxidation states and coordination environments. A specific application is concerned with the simultaneous reduction (topotactic oxide ion removal) and cation intercalation in layered oxide structures. These phases are potentially tunable lithium conductors for rechargeable battery technology. The proposed research program will provide unique training opportunities for students and prepares graduates for the renewable energy research environment in Canada.

基于氧化物的材料非常常见，并且在技术的小型化中发挥了至关重要的作用，并且为更高效率的器件开辟了途径。可充电电池的性能在过去十年中得到了显著改善，现在已成为所有类型设备（手机、计算机、汽车、医疗设备）中的可靠组件。固体氧化物燃料电池（SOFC）是一种高效的二次电源，可以耐受不同的燃料，几乎不需要维护。大多数这些器件的核心是无机固态材料，需要针对其各自的功能进行优化。对于能够提供可靠和有效性能同时具有经济竞争力的定制材料存在巨大的需求。本提案涉及这些功能性无机材料及其受控制备和加工。不幸的是，迄今为止，对固态材料的化学反应性和形成的了解非常少。事实上，功能材料的成功靶向制备往往取决于合成化学家的经验和直觉。我们的目标化合物是应用于能量转换的陶瓷，固体氧化物燃料电池（SOFC）技术的氧化物离子导体和可充电电池的新型层状锂导体。不幸的是，几乎没有合理的设计策略来合成无机材料。相同的材料组成可以产生具有不同性质的各种不同结构，传统上大多数金属氧化物是在高温（T > 1000°C）下直接制备的，而忽略了使用间接合成路线在较低温度下可获得的结构和功能多样性。Bieringer研究小组已经清楚地证明了在较低温度下可以获得大量的亚稳态结构。我们监测固态化学反应在真实的时间和衍生的反应途径，提供了扩展固体的结构-反应性关系。在较低的温度下，我们遇到了不同的氧化物缺陷结构（氧化物缺陷结构负责氧化物离子传导），具有作为固态电解质的潜在应用。在这个特别的建议中，我们的目标是进一步探索固态反应途径，试图建立可靠的结构-反应性关系，这将使功能性固态材料的合理设计。该提案的第二部分涉及低温拓扑异构反应，其中我们在反应期间仅修改部分结构。我们使用金属氧化物作为固态还原剂。这些使我们能够制备来自母体主体结构的亚稳产物，并表现出不寻常的氧化态和配位环境。一个具体的应用是与层状氧化物结构中的同时还原（topotactic氧化物离子去除）和阳离子嵌入有关。这些相是用于可再充电电池技术的潜在可调锂导体。拟议的研究计划将为学生提供独特的培训机会，并为加拿大可再生能源研究环境的毕业生做好准备。