"Atomically Precise Catalysis Studies with CLS Synchrotron for Sustainable, Efficient, and Environmentally-Friendly Chemical Processes"

“利用 CLS 同步加速器进行原子级精确催化研究，实现可持续、高效和环境友好的化学过程”

• 批准号: 262001-2012
• 负责人: Wang, Hui
• 金额: $ 1.46万
• 依托单位: University of Saskatchewan
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2015
• 资助国家: 加拿大
• 起止时间: 2015-01-01 至 2016-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=571198
• 关键词: Atomically; Precise; Catalysis; Studies; CLS

Catalytic chemical reaction processes play important roles in energy and chemical productions and environment protection technologies. The core of a catalytic chemical reaction process is the catalyst. The advances towards more sustainable, more efficient, and more environmentally-friendly chemical reaction processes need edge-cutting scientific research which leads to breakthrough in development of catalyst materials, where better atomically-precise understanding of catalytic phenomena using powerful synchrotron light source is essential. This proposal suggests a few continuing and initiating projects or directions that H. Wang's research group will pursue in the coming 5-year period of time. The first project is to build research facilities of in situ atomically-precise characterization of catalytic materials and catalytic reactions at the CLS (Canadian Light Source) with the help of other funds in applications. The beamlines possibly to use are HXMA (hard X-ray microanalysis) and SXRMB (soft X-ray microcharacterization beamline). Spectrum analysis tools such as XANES (X-ray absorption near-edge structure) and EXAFS (extended X-ray absorption fine structure) are also implemented. The second direction is to study the Ni-based catalysts for reactions such as CO2 reforming of methane, woody biomass conversions, and glycerol reforming. The similarity of the mechanism of carbon formation on Ni catalysts in these reactions will be investigated using synchrotron research facilities; and solutions to the common catalytic deactivation are to be discovered. The third is to develop the catalytic reactions in H2S splitting cycle, esp. the Bunsen reaction for a sustainable H2 production process for oil sand bitumen upgrading. And the fourth is to develop the internal-illuminated photocatalysts using the atomic layer deposition method. The establishment of the in situ catalysis research facilities at the CLS will benefit not only this program but the catalysis community in Canada. This program includes the training of 2 PhD students, 2 MSc students, 2 postdoctoral fellows under Wang's supervision, and others who come to access the facility at the CLS.

催化化学反应过程在能源化工生产和环境保护技术中发挥着重要作用。催化化学反应过程的核心是催化剂。朝着更可持续，更高效，更环保的化学反应过程的进步需要尖端的科学研究，这导致催化剂材料开发的突破，其中使用强大的同步加速器光源更好地原子精确理解催化现象是必不可少的。本建议提出了几个继续和启动项目或方向，H。王的研究小组将在未来5年的时间里继续研究。 第一个项目是在其他申请基金的帮助下，在CLS（加拿大光源）建立原位原子精确表征催化材料和催化反应的研究设施。可能使用的光束线是HXMA（硬X射线显微分析）和SXRMB（软X射线显微表征光束线）。还实现了XANES（X射线吸收近边结构）和EXAFS（扩展X射线吸收精细结构）等光谱分析工具。第二个方向是研究用于甲烷CO2重整、木质生物质转化和甘油重整等反应的镍基催化剂。在这些反应中，镍催化剂上的碳形成机制的相似性将使用同步加速器研究设施进行研究，并发现常见的催化失活的解决方案。第三是开发H2S裂解循环中的催化反应，特别是本生反应，以实现油砂沥青改质的可持续制氢工艺。第四，采用原子层沉积法制备内照射型光催化剂。 在CLS建立原位催化研究设施不仅有利于该计划，而且有利于加拿大的催化社区。该计划包括2名博士生，2名硕士生，2名博士后研究员在王的监督下，以及其他谁来访问CLS的设施的培训。