New catalytic reduction and coupling methods

新的催化还原和偶联方法

• 批准号: 326899-2012
• 负责人: Nikonov, Georgii
• 金额: $ 3.28万
• 依托单位: Brock University
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2016
• 资助国家: 加拿大
• 起止时间: 2016-01-01 至 2017-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=595164
• 关键词: New; catalytic; reduction; coupling; methods

Catalysis is involved in a large number of industrial processes in the petroleum, energy production, chemicals production, and the food industry sectors. It is essential in areas as diverse as gasoline production, control of auto emissions, production of polymers, synthesis of pharmaceuticals and food processing. Catalysis is a very important phenomenon, accounting (by some estimates) directly and indirectly for 20-25% of GDP of industrialised countries. Many of these catalytic processes are mediated by late transition metals, such as rhodium and platinum, that suffer from increasing prices and recognized toxicity (e.g. Speier's hydrosilylation catalyst H2PtCl6 and Wilkinson's hydrogenation catalyst (Ph3P)3RhCl).

催化参与了石油，能源生产，化学生产和食品工业领域的大量工业过程。在汽油生产，自动排放，聚合物的产生，药物合成和食品加工等多样性的地区至关重要。催化是一个非常重要的现象，在20-25％的工业化国家中，（据估计）（据估计）会计（一些估计）。这些催化过程中的许多是由晚期过渡金属（例如犀牛和铂）介导的。