Functionalized Polydicyclopentadiene: Reduction to Commercially Viable Pratice (I2I Phase 1)

官能化聚双环戊二烯：还原为商业上可行的做法（I2I 第 1 阶段）

• 批准号: 501981-2016
• 负责人: Wulff, Jeremy
• 金额: $ 9.11万
• 依托单位: University of Victoria
• 依托单位国家: 加拿大
• 项目类别: Idea to Innovation
• 财政年份: 2016
• 资助国家: 加拿大
• 起止时间: 2016-01-01 至 2017-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=609059
• 关键词: Functionalized; Polydicyclopentadiene; Reduction; Commercially; Viable

Polydicyclopentadiene (PDCPD) is a tough, heavily crosslinked thermoset polymer that is produced via ring-opening cross-metathesis polymerization (ROMP) from an earth-abundant feedstock isolated in large quantities (~400 million pounds annually) by the petrochemical industry. The extensive network of crosslinks gives PDCPD a very high impact resistance, good resistance to chemical corrosion, and a high heat deflection temperature. These properties make PDCPD very valuable for making automotive body panels used on heavy-duty vehicles. Unfortunately, several material limitations - each of which relates to polydicyclopentadiene's lack of chemical functionality - have precluded a deeper market penetration.

聚双环戊二烯(PDCPD)是一种坚韧、高度交联的热固性聚合物，通过开环交叉复分解聚合(ROMP)从石油化工行业大量分离的地球上丰富的原料(每年约4亿磅)中生产出来。广泛的交联网络使PDCPD具有非常高的抗冲击性、良好的耐化学腐蚀性和较高的热变形温度。这些特性使PDCPD在制造用于重型车辆的汽车车身覆盖件方面非常有价值。不幸的是，几种材料的限制--每一种都与聚双环戊二烯缺乏化学功能有关--阻碍了更深层次的市场渗透。