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Functional ionic liquid electrolytes

功能性离子液体电解质

基本信息

批准号：
RGPIN-2014-05743
负责人：
Rochefort, Dominic
金额：
$ 2.48万
依托单位：
Université de Montréal
依托单位国家：
加拿大
项目类别：
Discovery Grants Program - Individual
财政年份：
2016
资助国家：
加拿大
起止时间：
2016-01-01 至 2017-12-31
项目状态：
已结题

来源：
https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=611820
关键词：
Functional ionic liquid electrolytes

项目摘要

Electrolytes based on functional ionic liquids can potentially outperform traditional solvents by combining the exceptional stability of ionic liquids with a reactive group that can perform specific tasks. The research program proposed aims at developing new knowledge on the fundamental properties of such functional ionic liquids. Understanding how the structure of ionic liquids affects the electrode processes will be essential to orient the design of functional ionic liquids electrolytes that promote these processes. The development of advanced electrolytes based on functional ionic liquids will impact many electrochemical systems applied in energy storage and conversion devices, electrocatalytic synthesis, and sensors. The research proposed will expand in particular our efforts on electrolytes for energy storage devices which include electrochemical capacitors and batteries. Two types of functional ionic liquids are central to this work. Ionic liquids with proton exchange ability and electroactive ionic liquids, which are obtained by the addition of a redox moiety on an ionic component. The short to mid-term objectives consist in the investigation of i-the structure of the ionic liquid phases in the bulk and at various surfaces, ii-the heterogeneous proton transfer between protic ionic liquids and metal/metal oxide electrodes, and iii-the electron transfer reactions in neat (pure) redox ionic liquids. The long term objective of the program is the advancement of energy storage systems by perfecting the matching of electrode materials and electrolytes.

基于功能性离子液体的电解质通过结合离子液体的特殊稳定性和可以执行特定任务的反应基团，有可能超越传统溶剂。提出的研究计划旨在开发有关这种功能性离子液体基本性质的新知识。了解离子液体的结构如何影响电极过程对于定向设计促进这些过程的功能性离子液体电解质至关重要。基于功能化离子液体的先进电解质的发展将影响许多应用于能量存储和转换装置、电催化合成和传感器的电化学系统。提出的研究将特别扩大我们在包括电化学电容器和电池在内的能量存储设备电解质方面的努力。两种功能型离子液体是这项工作的核心。具有质子交换能力的离子液体和电活性离子液体，它们是通过在离子组分上添加氧化还原部分而得到的。短期到中期的目标包括研究i-离子液体在整体和不同表面的结构，ii-质子液体和金属/金属氧化物电极之间的非均相质子转移，以及iii-纯（纯）氧化还原离子液体中的电子转移反应。该项目的长期目标是通过完善电极材料和电解质的匹配来推进储能系统。