Redox Active Heterocycles: From Free Radicals to Non-Innocent Ligands

氧化还原活性杂环：从自由基到非无辜配体

• 批准号: RGPIN-2015-05523
• 负责人: Rawson, Jeremy
• 金额: $ 2.55万
• 依托单位: University of Windsor
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2017
• 资助国家: 加拿大
• 起止时间: 2017-01-01 至 2018-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=632652
• 关键词: Redox; Active; Heterocycles; Free; Radicals

The research undertaken in my group, supported through an NSERC Canada Research Chair, has focused on preparing new 'responsive' organic materials in which the physical (magnetic) properties respond to changes in the surroundings such as heat, light or pressure. During the last few years our research in this area has uncovered several new areas of coordination chemistry which are not directly related to our research on organic materials but provide exciting opportunities to open up new avenues of research. We seek funding through this Discovery Grant to more fully explore these new areas of chemistry. Whilst we can foresee potential benefits arising from this research in the medium-long term, the objective of the current application is to fully develop the underpinning chemistry in order that we can position ourselves to exploit the science in the fullness of time.

在NSERC加拿大研究主席的支持下，我的小组进行的研究集中在制备新的“响应”有机材料上，这种材料的物理（磁性）特性会对周围环境（如热、光或压力）的变化做出反应。在过去的几年里，我们在这一领域的研究发现了几个新的配位化学领域，这些领域与我们对有机材料的研究没有直接关系，但为开辟新的研究途径提供了令人兴奋的机会。我们通过这项发现基金寻求资金，以更充分地探索这些新的化学领域。虽然我们可以预见这项研究在中长期内会带来潜在的好处，但当前应用的目标是充分发展基础化学，以便我们能够在充分的时间内利用科学。