Magnetic, electronic and optical properties of multifunctional main group radicals

多功能主族自由基的磁、电子和光学性质

• 批准号: RGPIN-2020-04627
• 负责人: Rawson, Jeremy
• 金额: $ 4.66万
• 依托单位: University of Windsor
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2022
• 资助国家: 加拿大
• 起止时间: 2022-01-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=748482
• 关键词: Magnetic; electronic; optical; properties; multifunctional

Energy is increasingly expensive and a "do more for less" approach is already used in a variety of devices based on lightweight, flexible, low power technology, including organic light emitting diodes in screen displays and low cost organic solar cells for light-harvesting. The use of organic components in modern devices arises from their flexibility and cheap processing, alongside an ability to tailor their properties through chemical modification. Despite considerable advances, there are many fundamental challenges still to be met in the field of solid-state organic electronics. For crystalline organic solids, the solid-state architecture ultimately dictates their function. Yet controlling the arrangement of molecules in the solid state continues to be a major challenge, determined by a set of rather weak interactions between molecules. The identification of more robust interactions, so-called "supramolecular synthons", has the potential to lead to new materials programmed to configure molecules in specific arrangements in which their properties are optimized. Our research focuses on a family of organic molecules with potentially important electronic (semiconducting, optical and magnetic) properties. Our long-term objectives are to identify and implement strong supramolecular interactions within this family of organic molecules to control their solid-state structures and optimize their properties. In the current proposal, we aim to: a)Identify and implement robust interactions between different molecules which can be used to prepare `co-crystals' in which each molecule brings different behavior (light addressable, magnetic, conducting). We will then explore the interplay between the behavior of each component in the new composite material. b)Develop multi-functional molecules in which optical and electronic properties are installed into the same molecule. We will then investigate independent or cooperative behavior between the components. c)Prepare a new family of electronically addressable molecules known as "non-innocent ligands" which can bind to metals. We will examine the magnetic interplay between the ligand and the metal and investigate how this can be optically addressed. This fundamental research will identify approaches to address contemporary challenges in molecular materials science, lead to the fabrication and testing of prototype devices, while simultaneously training high caliber scientists who can contribute to the Canadian workforce.

能源越来越昂贵，并且“少花钱多办事”的方法已经用于基于轻量、灵活、低功率技术的各种设备，包括屏幕显示器中的有机发光二极管和用于光捕获的低成本有机太阳能电池。有机组件在现代设备中的使用源于其灵活性和廉价的加工，以及通过化学改性来定制其特性的能力。尽管取得了相当大的进展，但在固态有机电子领域仍有许多根本性的挑战有待解决。对于结晶有机固体，固态结构最终决定了它们的功能。然而，控制固态分子的排列仍然是一个重大挑战，这是由分子之间一系列相当弱的相互作用决定的。识别更强大的相互作用，所谓的“超分子离子”，有可能导致新的材料编程配置分子在特定的安排，其中它们的性能得到优化。我们的研究重点是具有潜在重要电子（半导体，光学和磁性）特性的有机分子家族。我们的长期目标是在这个有机分子家族中识别和实现强超分子相互作用，以控制其固态结构并优化其性能。在目前的提案中，我们的目标是：a）识别和实现不同分子之间的强大相互作用，这些分子可用于制备“共晶体”，其中每个分子带来不同的行为（光寻址、磁性、导电）。然后，我们将探索新复合材料中每个组件的行为之间的相互作用。 B）开发多功能分子，其中光学和电子特性安装到同一分子中。然后，我们将研究组件之间的独立或合作行为。c）制备一种新的电子寻址分子家族，称为“非无辜配体”，可以与金属结合。我们将研究配体和金属之间的磁性相互作用，并研究如何通过光学方法解决这一问题。 这项基础研究将确定解决分子材料科学当代挑战的方法，导致原型设备的制造和测试，同时培养能够为加拿大劳动力做出贡献的高素质科学家。