Hypercoordinated and Cationic Main Group Organometallic Compounds —Synthesis and Catalysis

超配位和阳离子主族有机金属化合物→合成与催化

• 批准号: RGPIN-2017-04742
• 负责人: Fillion, Eric
• 金额: $ 2.55万
• 依托单位: University of Waterloo
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2017
• 资助国家: 加拿大
• 起止时间: 2017-01-01 至 2018-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=632686
• 关键词: Hypercoordinated; Cationic; Main; Group; Organometallic

This research program will contribute original knowledge to many areas of organometallic chemistry, catalysis, and organic synthesis by providing a better understanding of hypercoordinated and cationic Sn(IV) compounds. That knowledge will enable the development of new Sn(IV) organometallic compounds that will be employed as reagents and catalysts in the development of new synthetic methods. The design and development of main group metal-based catalysts represents a challenging and dynamic area in organometallic chemistry. That interest is mainly driven by the finding of novel reactivity typically associated with transition metals.

该研究计划将通过更好地了解对高度协调的SN（IV）化合物的理解，为有机金属化学，催化和有机合成的许多领域提供原始知识。这些知识将使新的SN（IV）有机金属化合物的开发能够开发为试剂和催化剂，以开发新的合成方法。主要基于金属的催化剂的设计和开发代表了有机金属化学中一个具有挑战性和动态的区域。这种兴趣主要是由于通常与过渡金属相关的新反应性的发现。