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Low-cost process of converting asphaltene into valuable graphene-like materials**

Low-cost process of converting asphaltene into valuable graphene-like materials**
将沥青质转化为有价值的类石墨烯材料的低成本工艺**
批准号:
532120-2018
负责人:
Li, Zhi
金额:
$3.16万
依托单位:
依托单位国家:
加拿大
项目类别:
Collaborative Research and Development Grants
财政年份:
2018
资助国家:
加拿大
项目状态:
已结题
起止时间:
2018-01-01 至 2019-12-31

项目摘要

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中文摘要
翻译
在油砂工业的沥青提取或升级过程中,沥青质通常具有极低或零值。沥青烯是一类由缩合芳环、环烷环和脂肪链组成的分子。传统的沥青质增值方法是将沥青质分子分解成较轻的馏分用于燃料应用,这是一个资本密集型的过程,并产生大量的温室气体排放。相反,该项目旨在开发一种绿色、可扩展和经济的工艺,将从沥青中分离出来的沥青质转化为类似石墨烯的碳纳米材料,其市场价值高达50美元/克。作为制造碳材料的原料,沥青质中的芳香核成为一个必不可少的优势:它最大限度地减少了石墨结构形成过程中C-C键重建的要求。该项目提出的沥青质“升级”技术将为加拿大油砂行业提供高附加值的沥青质解决方案。与广泛使用的化学气相沉积(CVD)方法和石墨剥离方法相比,该研究的成功部署使大规模生产类石墨烯碳的成本显著降低
英文摘要
Asphaltenes rejected in bitumen extraction or upgrading processes in oil sands industry usually has extremely low or zero value. Asphaltenes are a class of molecules consisting of condensed aromatic rings, naphthenic rings and aliphatic chains. A traditional wisdom of value -adds for asphaltene is to break the asphaltene molecules into lighter fractions for fuel application, which is capital intensive process and generates considerable GHG emissions. Instead, the proposed project is aimed to develop a green, scalable and economic process of converting asphaltenes separated from bitumen into graphene-like carbon nanomaterials with a market value up to ~$50/g. As feedstock to make carbon materials, the aromatic nucleus in asphaltene become an essential advantage: it minimizes the C-C bonds reconstruction requirements in the formation of the graphitic structure. The proposed asphaltene "upgrading" technology developed in the project will provide Canada's oil sands industry with a high value-added solution of asphaltene. The successful deployment of proposed research enables the large-scale production of graphene-like carbons at significantly lower cost compared to the widely used chemical vapor deposition (CVD) method and graphite-exfoliation method.**
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