Stoichiometry, hierarchical arrangement and kinetics of electrode reactions at novel multi-components electrocatalytic materials

新型多组分电催化材料电极反应的化学计量、分级排列和动力学

• 批准号: RGPIN-2019-05975
• 负责人: Mohamedi, Mohamed
• 金额: $ 1.75万
• 依托单位: Institut national de la recherche scientifique
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2020
• 资助国家: 加拿大
• 起止时间: 2020-01-01 至 2021-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=715870
• 关键词: Stoichiometry; hierarchical; arrangement; kinetics; electrode

The depletion of fossil fuel reserves and serious environmental issues has created tremendous energy challenges. It is now undeniable that electrochemistry- the interchange of chemical and electrical energy- is about to play a major role in energy production. As a clean, sustainable energy technology, direct ethanol fuel cells (DEFCs) have emerged as highly promising low carbon power sources for vehicles and as alternatives to rechargeable batteries in portable electronic devices. Yet, the commercialization of DEFCs is hindered by their low anode catalyst activities and the production of partial oxidation byproducts. In addition, proton exchange membranes-DEFCs are considered too bulky and costly, and they can be damaged by high concentrations of ethanol, known as the ethanol crossover effect. Our long-term objective is to develop membraneless mixed-reactants DEFCs (novel technology) with efficiency higher than 60%. Over the next five years, the main objective of our work is to develop and gain insights in the synthesisstructurecatalytic activity relationships of novel nanostructured highly active and efficient multicomponent anode catalysts for the electrocatalytic oxidation of ethanol (Theme I). Efforts will be focused on the addition of co-catalysts to platinum. We will choose materials composed of abundant and inexpensive metal oxide materials combined with ultra-low amounts of platinum and rhodium. We expect to discover the optimal structural arrangements of the atoms of the three components in the surface and bulk of the final active catalyst to maximize activity and selectivity. We will also develop selective cathode catalyst that is electroactive towards oxygen reduction reaction while tolerant to high concentrations of ethanol (Theme II). Considering that the size of oxygen molecule is much smaller than that of ethanol, our idea is develop a superficial material layer through which oxygen molecules can easily diffuse and be reduced at the platinum beneath layer surface while ethanol molecules remain impeded at the surface of the superficial layer. Like this higher ethanol concentrations could be used and superior electrochemical performance would be achieved. The results of this proposal will address Canada's research priority in the development of advanced nanomaterials based electrochemical clean/green technologies to deal with increasingly critical energy and environmental challenges as well as climate change, while training highly qualified personnel to exploit these opportunities. As to the fundamental issues, these studies will assist in establishing firm correlations between interfacial structures, compositions, and understanding of mechanistic aspects of new classes of catalytic materials. In addition, this proposed research program will be important to commercial applications in Canada such as, consumers' portable electronics and transport, or to specific users for road safety fuel cell-based sensors for ethanol detection.

化石燃料储量的枯竭和严重的环境问题已经造成了巨大的能源挑战。现在不可否认的是，电化学-化学能和电能的交换-即将在能源生产中发挥重要作用。作为一种清洁、可持续的能源技术，直接乙醇燃料电池（DEFC）已成为非常有前途的车用低碳电源和便携式电子设备中可充电电池的替代品。然而，DEFC的商业化受到其低阳极催化剂活性和部分氧化副产物的产生的阻碍。此外，质子交换膜-DEFC被认为过于庞大和昂贵，并且它们可能被高浓度的乙醇破坏，称为乙醇交叉效应。我们的长期目标是开发效率高于60%的无膜混合反应物DEFC（新技术）。 在接下来的五年里，我们工作的主要目标是开发和获得见解的合成结构催化活性关系的新型纳米结构的高活性和高效的多组分阳极催化剂的电催化氧化乙醇（主题I）。努力的重点将是在铂中加入助催化剂。我们将选择由丰富而廉价的金属氧化物材料与超低量的铂和铑组合而成的材料。我们期望发现最终活性催化剂的表面和本体中三种组分的原子的最佳结构排列，以最大化活性和选择性。我们还将开发对氧还原反应具有电活性同时耐受高浓度乙醇的选择性阴极催化剂（主题II）。考虑到氧分子的尺寸比乙醇小得多，我们的想法是开发一种表面材料层，通过该表面材料层，氧分子可以容易地扩散并在铂下层表面被还原，而乙醇分子在表面层的表面处被阻挡。像这样，可以使用更高的乙醇浓度，并且可以实现上级电化学性能。 该提案的结果将涉及加拿大在开发基于先进纳米材料的电化学清洁/绿色技术方面的研究重点，以应对日益严峻的能源和环境挑战以及气候变化，同时培训高素质人员以利用这些机会。至于基本问题，这些研究将有助于建立牢固的界面结构，组合物之间的相关性，并了解新类别的催化材料的机械方面。此外，这项拟议的研究计划将是重要的商业应用在加拿大，如消费者的便携式电子产品和运输，或特定用户的道路安全燃料电池为基础的传感器，用于乙醇检测。