Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
基本信息
- 批准号:RGPIN-2020-05486
- 负责人:
- 金额:$ 2.77万
- 依托单位:
- 依托单位国家:加拿大
- 项目类别:Discovery Grants Program - Individual
- 财政年份:2020
- 资助国家:加拿大
- 起止时间:2020-01-01 至 2021-12-31
- 项目状态:已结题
- 来源:
- 关键词:
项目摘要
The central focus of my research program is to advance the fundamental chemistry and applications of sustainable biomass resources that are abundant, inexpensive, and non-food based into commercial polymers with properties and characteristics suitable to replace current petroleum-based resins. The Biomass resource, recovered as waste product from forestry and the Pulp and Paper Industry, in the form of Rosin acids or Lignin by-products will be used exclusively in this effort. The primary focus of this application will target commercial Bisphenol A polymer (BPA) replacement. Canada, along with the Europe, as well as several US states are targeting a complete ban of this chemical linked to various human health problems. The most prevalent applications of BPA are in the construction industry (sheeting), packaging, automotive parts, toys, compact discs, DVDs, safety equipment, LCD screens, coatings, consumer parts, inks, toners, and 3D Printing filament. Many of the properties associated with these products include high performance, hydrophobic, clarity, hydrolytic stability, oxygen permeability, and above all, low cost.
Our proposed research program, outlines novel chemistry through alternative process, methodology, and HPQ training for future graduates, that can impact commercially viable sustainable alternatives to petro-based polymers. Our research program will be directed towards the synthesis, development, properties and processing of sustainable building block monomers and corresponding polymers. The overall aim of this project is to develop the chemistry and engineering required to transform waste biomass into a commodity polymer, specifically polyesters, polycarbonates, polyamides and polyurethanes. These polymers are typically produced from building blocks comprised primarily of di-functional monomers via polycondensation reactions. The proposed aforementioned Biomass sources comprised of Rosin acids, and lignin degradation by-products, are mostly mono-functional or lack any functionality, and the key to this research program is to convert these sustainable materials into difunctional monomers, followed by polymerization via cost-effective means. We will apply the principles of Green Chemistry and Engineering into all of our designs, for both monomer and polymerization process by bulk reactions as well as reactive extrusion to avoid the use of organic solvents. Reactive extrusion is a cost-effective and environmentally-friendly method to produce new materials with enhanced performance properties. At present, reactive extrusion allows in-situ polymerization, modification/functionalization of polymers or chemical bonding of two (or more) immiscible phases. Although reactive extrusion has been known for many years, its application for processing of bio-based polymer blends and composites is a relatively new direction of scientific research.
我的研究计划的中心重点是促进可持续生物质资源的基础化学和应用,这些资源丰富、廉价、以非食品基为基础,制成具有适合取代当前石油基树脂的性能和特性的商业聚合物。作为林业和制浆造纸工业废物回收的生物质资源,将以松香酸或木质素副产品的形式专门用于这项工作。这一应用的主要焦点将是商用双酚A聚合物(BPA)的替代品。加拿大、欧洲以及美国的几个州正致力于全面禁止这种与各种人类健康问题有关的化学物质。双酚A最普遍的应用是建筑行业(薄片)、包装、汽车零部件、玩具、光盘、DVD、安全设备、LCD屏幕、涂料、消费品、油墨、碳粉和3D打印丝。与这些产品相关的许多特性包括高性能、疏水性、透明度、水解性稳定性、透氧性,最重要的是低成本。
我们建议的研究计划通过替代工艺、方法和面向未来毕业生的HPQ培训概述了新的化学,这些可能会影响石油聚合物的商业上可行的可持续替代品。我们的研究计划将致力于可持续积木单体和相应聚合物的合成、开发、性能和加工。该项目的总体目标是开发将废物生物质转化为商品聚合物所需的化学和工程技术,特别是聚酯、聚碳酸酯、聚酰胺和聚氨酯。这些聚合物通常是由主要由双功能单体通过缩聚反应组成的积木生产的。上述提出的由松香酸和木质素降解副产物组成的生物质来源大多是单官能团或缺乏任何官能团,这项研究计划的关键是将这些可持续材料转化为双官能团单体,然后通过经济有效的方法进行聚合。我们将把绿色化学和工程的原则应用到我们的所有设计中,包括单体和聚合过程,通过本体反应和反应挤出来避免使用有机溶剂。反应挤出是一种经济有效、环境友好的方法,可以生产性能更好的新材料。目前,反应挤出允许聚合物的原位聚合、改性/官能化或两个(或多个)不相容相的化学结合。反应挤出技术应用于生物基聚合物共混物和复合材料的加工是一个相对较新的科学研究方向。
项目成果
期刊论文数量(0)
专著数量(0)
科研奖励数量(0)
会议论文数量(0)
专利数量(0)
数据更新时间:{{ journalArticles.updateTime }}
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
数据更新时间:{{ journalArticles.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ monograph.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ sciAawards.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ conferencePapers.updateTime }}
{{ item.title }}
- 作者:
{{ item.author }}
数据更新时间:{{ patent.updateTime }}
Sacripante, Guerino其他文献
Sacripante, Guerino的其他文献
{{
item.title }}
{{ item.translation_title }}
- DOI:
{{ item.doi }} - 发表时间:
{{ item.publish_year }} - 期刊:
- 影响因子:{{ item.factor }}
- 作者:
{{ item.authors }} - 通讯作者:
{{ item.author }}
{{ truncateString('Sacripante, Guerino', 18)}}的其他基金
Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
- 批准号:
RGPIN-2020-05486 - 财政年份:2022
- 资助金额:
$ 2.77万 - 项目类别:
Discovery Grants Program - Individual
Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
- 批准号:
RGPIN-2020-05486 - 财政年份:2021
- 资助金额:
$ 2.77万 - 项目类别:
Discovery Grants Program - Individual
Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
- 批准号:
DGECR-2020-00473 - 财政年份:2020
- 资助金额:
$ 2.77万 - 项目类别:
Discovery Launch Supplement
A Thermogravimetric Analyzer with Fourier Transform Infrared Capability
具有傅里叶变换红外功能的热重分析仪
- 批准号:
RTI-2021-00761 - 财政年份:2020
- 资助金额:
$ 2.77万 - 项目类别:
Research Tools and Instruments
相似海外基金
Development of catalysts for effective synthesis of nitrogen-containing polymers derived from chitin
开发有效合成甲壳素含氮聚合物的催化剂
- 批准号:
23K13780 - 财政年份:2023
- 资助金额:
$ 2.77万 - 项目类别:
Grant-in-Aid for Early-Career Scientists
LEAPS-MPS: Biomass-Derived Depolymerizable and Degradable Polymers as Sustainable Materials
LEAPS-MPS:生物质衍生的可解聚和可降解聚合物作为可持续材料
- 批准号:
2316842 - 财政年份:2023
- 资助金额:
$ 2.77万 - 项目类别:
Standard Grant
Platform technologies for sustainable manufacturing of smart textiles using natural polymers and bio-derived green solvents
使用天然聚合物和生物衍生绿色溶剂可持续制造智能纺织品的平台技术
- 批准号:
567994-2022 - 财政年份:2022
- 资助金额:
$ 2.77万 - 项目类别:
Postdoctoral Fellowships
CAS: Terpene-Derived Polymers as Platforms for Structure-Property Studies of Sustainable Materials
CAS:萜烯衍生聚合物作为可持续材料结构性能研究的平台
- 批准号:
2206955 - 财政年份:2022
- 资助金额:
$ 2.77万 - 项目类别:
Continuing Grant
Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
- 批准号:
RGPIN-2020-05486 - 财政年份:2022
- 资助金额:
$ 2.77万 - 项目类别:
Discovery Grants Program - Individual
Sustainable polymers derived from plant oils
来自植物油的可持续聚合物
- 批准号:
2585422 - 财政年份:2021
- 资助金额:
$ 2.77万 - 项目类别:
Studentship
Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
- 批准号:
RGPIN-2020-05486 - 财政年份:2021
- 资助金额:
$ 2.77万 - 项目类别:
Discovery Grants Program - Individual
Redox-Active Polymers Derived from Formazanate Dyes
源自甲磺酸盐染料的氧化还原活性聚合物
- 批准号:
535360-2019 - 财政年份:2021
- 资助金额:
$ 2.77万 - 项目类别:
Alexander Graham Bell Canada Graduate Scholarships - Doctoral
Redox-Active Polymers Derived from Formazanate Dyes
源自甲磺酸盐染料的氧化还原活性聚合物
- 批准号:
535360-2019 - 财政年份:2020
- 资助金额:
$ 2.77万 - 项目类别:
Alexander Graham Bell Canada Graduate Scholarships - Doctoral
Novel Polymers Derived from Sustainable Building Block Monomers
源自可持续构建单元单体的新型聚合物
- 批准号:
DGECR-2020-00473 - 财政年份:2020
- 资助金额:
$ 2.77万 - 项目类别:
Discovery Launch Supplement