Differential Scanning Calorimeter/Thermal Gravimetric Analysis

差示扫描量热仪/热重分析

• 批准号: RTI-2021-00578
• 负责人: Nazar, Linda
• 金额: $ 9.62万
• 依托单位: University of Waterloo
• 依托单位国家: 加拿大
• 项目类别: Research Tools and Instruments
• 财政年份: 2020
• 资助国家: 加拿大
• 起止时间: 2020-01-01 至 2021-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=718849
• 关键词: Differential; Scanning; Calorimeter; Thermal; Gravimetric

Solid-state electrochemistry research is concerned with the relationship between the structure of a material and its electrochemical properties. In our lab, we target our properties towards ion and electron transport in solids. Aside from having fundamental interest in their study, these are also critical properties for the development of new lithium-ion battery electrode and solid state electrolyte materials which form the major part of our research. Materials under study include lithium metal oxides, sulfides, chlorides and inorganic/organic polymer composites. Developing new materials requires that the structure and composition of the material be fully characterized; for this we need to use a suite of physical and analytical techniques, of which the combination of differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA) plays an absolutely pivotal role. We use gravimetric and differential scanning calorimetry thermal analysis methods routinely to determine the composition of our solids; the former involves heating the material to measure mass losses and/or gains that are incurred as a result of change of composition. These changes can involve loss or gain of elements (oxygen, halide, etc) from the structure, and/or loss of water, and organic components. Structural changes that occur without mass change are observed as thermal events in the differential calorimeter, which proceed with heat gain or loss measured with respect to a reference. This is used to determine where a combination of precursors or an amorphous material crystallizes (so that the correct protocol can be established in a furnace) and/or to evaluate the thermal stability of a material. DSC technology also measures the energy exchange between the material under analysis and its environment, which is a very useful thermodynamic value that can be converted to enthalpy values to help determine the properties of the new material of interest. In summary, funds are requested to acquire a simultaneous differential scanning calorimeter/thermal gravimetric analysis apparatus to give us a crucial analytical tool for materials characterization for energy storage (aka battery) materials.

固态电化学研究关注的是材料的结构与其电化学性能之间的关系。在我们的实验室里，我们的目标是离子和电子在固体中的传输。除了对他们的研究有基本的兴趣外，这些也是开发新的锂离子电池电极和固态电解质材料的关键特性，这是我们研究的主要部分。研究的材料包括锂金属氧化物、硫化物、氯化物和无机/有机聚合物复合材料。开发新材料要求充分表征材料的结构和组成；为此，我们需要使用一套物理和分析技术，其中差示扫描量热法（DSC）和热重分析（TGA）的结合起着绝对关键的作用。