Utilizing Organic Chemistry to Address Quantum Information Science Applications

利用有机化学解决量子信息科学应用

• 批准号: RGPIN-2022-03709
• 负责人: Chernick, Erin
• 金额: $ 1.45万
• 依托单位: University of Victoria
• 依托单位国家: 加拿大
• 项目类别: Discovery Grants Program - Individual
• 财政年份: 2022
• 资助国家: 加拿大
• 起止时间: 2022-01-01 至 2023-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=747821
• 关键词: Utilizing; Organic; Chemistry; Address; Quantum

The Chernick group specializes in synthetic organic chemistry of complex, highly functional conjugated systems for quantum information science (QIS) applications. A substantial amount of research in organic chemistry has focused on the tailored synthesis and characterization of molecules that undergo electron/energy processes for use in renewable energy applications, such as optoelectronic devices that rely upon charge transfer processes. This research has revealed key challenges that arise when the operating size of a device drops below the 10 nm size range. To reduce the size of the microchips that sustain the operation of a computing device, advancement to a single-molecule quantized regime is necessary. Hence, the research field of renewable energy devices has branched into the field of QIS, which is the study of quantum phenomena covering research disciplines pertaining to quantum teleportation, quantum entanglement, and quantum computation. The organic molecules the Chernick group synthesize are specifically designed to act as solar energy sensors to produce electronically excited states that can populate different spin states and/or undergo a charge transfer process. The generated charge transfer species contains an orbital lacking an electron (radical cation state) and an orbital with an additional electron (radical anion state) within the same molecule. These electrons can be spin-paired in either a singlet or triplet state. When these unpaired spin-states interact in an intramolecular manner with a covalently bound neighboring unpaired electron in the form of a stable free radical, multiple spin-states can be populated. This opens the door to the opportunity of creating single molecule organic quantum bits for QIS applications.

Chernick集团专门从事量子信息科学（QIS）应用的复杂，高功能共轭体系的合成有机化学。有机化学中的大量研究集中在可再生能源应用中使用的经历电子/能量过程的分子的定制合成和表征，例如依赖于电荷转移过程的光电器件。这项研究揭示了当器件的工作尺寸降至10 nm以下时所面临的关键挑战。为了减小维持计算设备的操作的微芯片的尺寸，有必要向单分子量子化机制发展。因此，可再生能源设备的研究领域已经分支到QIS领域，QIS是对量子现象的研究，涵盖与量子隐形传态、量子纠缠和量子计算有关的研究学科。Chernick团队合成的有机分子被专门设计为太阳能传感器，以产生电子激发态，这些电子激发态可以填充不同的自旋状态和/或经历电荷转移过程。所产生的电荷转移物质在同一分子内包含缺少电子的轨道（自由基阳离子态）和具有额外电子的轨道（自由基阴离子态）。这些电子可以在单重态或三重态中自旋配对。当这些未成对的自旋态以分子内的方式与共价结合的相邻未成对电子以稳定的自由基的形式相互作用时，可以填充多个自旋态。这为QIS应用创造单分子有机量子比特的机会打开了大门。