Dynamic Repellency, Wettability and Capillarity as Primary Drivers for Water Flow and Chemical Transport in Soils and Groundwater in the Critical Zone

临界带从土壤表面延伸到区域地下水位以下的地下水，支持几乎所有的陆地生命，并包含大部分陆地生物量。我们能够更好地定量预测地下水流、化学运动和气体交换，这对于准确评估许多环境问题以及相关的管理和/或补救方案至关重要。鉴于我们对即将到来的气候变化对温度和降水的影响的最佳估计，对控制水的运动以及土壤和地下水中化学污染物的命运和运输的机制和过程有更好的基本理解变得更加迫切。当空气（气相）和水（多相流体）在地下共存时，我们目前的知识和定量预测水流、污染物运移的能力仍然非常有限。这是非饱和土壤和临界区浅层地下水中被困空气的情况，特别是当土壤和岩石的润湿性/驱避性是动态的（时间依赖的）时。当溢出的污染物具有表面活性（表面活性剂）特性时，它受到严格限制。特别敏感的土壤的例子是具有高有机质含量的防水干燥土壤，野火后土壤和被石油产品和工业溶剂污染的土壤。随着时间的推移，许多环境污染物和天然存在的化合物作为表面活性化合物（表面活性剂），大大改变了空气-水界面的表面张力、固体表面的润湿性和接触角，这使得润湿性和毛细性的问题变得复杂。我在溶质浓度依赖性毛细作用、接触角动力学和分数润湿性对土壤水分行为的影响方面的创新研究和出版物方面拥有丰富的研究经验和长期的国际声誉。这些贡献、知识和专业知识是拟议研究的基础。科学的方法将结合仪器齐全的实验室流动池实验、数学模型开发和实地研究。未来5年的主要目标成果将是开发概念数据集、概念模型、一阶动态水力函数和土壤中水渗透和保留的定量一阶数学模型，以表达动态润湿性和毛细性。这项研究将为专家和非专家（如环境修复专家、森林学家、生态水文学家）生成简单的一阶实用模型，以便能够更准确、更可靠地计算水渗透、污染物运输行为以及由此产生的土壤保水、地下水补给和污染物迁移和命运。

The critical zone which extends form the soil surface down to groundwater below the regional water table supports almost all terrestrial life and contains most of the terrestrial biomass. Our ability to better quantitatively predict water flow, chemical movement and gas exchange in the subsurface is essential and foundational to accurately assessing many environmental problems and associated management and/or remediation schemes. A better fundamental understanding of mechanisms and processes controlling the movement of water and the fate and transport of chemical contaminants in the soil and groundwater is ever more urgent given our best estimates of pending climate change impacts on temperatures and precipitation. Our current knowledge and ability to quantitatively predict water flow, contaminant transport remain critically limited when both air (gas-phase) and water coexist (multi-phase fluids) in the subsurface.  This is the case in unsaturated soils and entrapped air in shallow groundwaters of the critical zone, and particularly limited when the wettability/repellency of the soils and rocks is dynamic (time-dependent). It is critically limited when spilled contaminants have surface active (surfactant) properties.  Examples of soils which are exceptionally sensitive are water repellent dry soils with high organic matter contents, post wildfire soils, and soils contaminated by petroleum products and industrial solvents. The problem of wettability and capillarity changing over time are complicated by the fact that numerous environmental contaminants and naturally occurring compounds act as surface active compounds (surfactants) which substantially change the surface tension at the air water interface, the wettability and contact angle at solid surfaces. I have extensive research experience and a long international reputation for my innovative research and publications on solute concentration dependent capillarity, contact angle dynamics and fractional wettability effects on soil water behavior. Those contributions, knowledge and expertise are foundational to the proposed research. The scientific approach will combine well instrumented laboratory-based flow cell experiments, mathematical model development, and field studies. The primary targeted outcomes over the next 5 years will be to develop proof of concept data sets, conceptual models, first-order dynamic hydraulic functions and quantitative first-order mathematical models of water infiltration and retention in soils expressing dynamic wettability and capillarity. The research will generate simple first-order practical models for specialists and non-specialists (e.g. environmental remediation specialists, foresters, eco-hydrologists) to be able to calculate more accurate and reliable water infiltration, contaminant transport behaviours and resultant soil water retention, groundwater recharge and contaminant migration and fate.